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Synthesis and Optical Properties of New S-Derivatives of 5,5′-(1,4-Phenylene)bis(4H-1,2,4-triazole-3-thiol) and 5,5′,5″-(Benzene-1,3,5-triyl)tris(4H-1,2,4-triazole-3-thiol)

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Abstract

A simple one-pot synthetic method for novel S-alkenyl and propargyl derivatives of 5,5′-(1,4-phenylene)-bis(4H-1,2,4-triazole-3-thiol) and 5,5′,5″-(benzene-1,3,5-triyl)tris(4H-1,2,4-triazole-3-thiol) has been developed. Absorption and luminescence properties of the synthesized compounds have been estimated, and the fluorescence quantum yields have been determined.

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Funding

This work was performed with financial support from the Ministry of Science and Higher Education of the Russian Federation (grant no. 4.9665.2017/8.9) and within the framework of the state assignment (no. 075-00578-19-00).

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Authors and Affiliations

  1. South Ural State University, Chelyabinsk, 454080, Russia

    E. S. Il’inykh & D. G. Kim

  2. I.Ya. Postovskii Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, Yekaterinburg, 620108, Russia

    M. S. Valova & O. V. Fedorova

Authors
  1. E. S. Il’inykh
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  2. D. G. Kim
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  3. M. S. Valova
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  4. O. V. Fedorova
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Correspondence to E. S. Il’inykh.

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Il’inykh, E.S., Kim, D.G., Valova, M.S. et al. Synthesis and Optical Properties of New S-Derivatives of 5,5′-(1,4-Phenylene)bis(4H-1,2,4-triazole-3-thiol) and 5,5′,5″-(Benzene-1,3,5-triyl)tris(4H-1,2,4-triazole-3-thiol). Russ J Gen Chem 89, 2571–2576 (2019). https://doi.org/10.1134/S1070363219120375

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