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Synthesis and Luminescent Properties of Eu3+, Gd3+, and Tb3+ Complexes with Quinoline-4-carboxylic Acids

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Abstract

New complex compounds LnL3·nH2O (n = 5–10) have been synthesized on the basis of Eu3+, Gd3+, and Tb3+ salts and quinoline-4-carboxylic acid derivatives obtained via the Pfitzinger reaction. Composition and structure of the ligands and the resulting complex compounds have been confirmed by NMR and IR spectroscopy, thermogravimetry, and complexometric titration. Europium complex with 1,2,3,4-tetrahydroacridine-9-carboxylic acid has exhibited efficient luminescence.

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Funding

This study was financially supported by the Ministry of Education and Science of Russian Federation (project no. 4.5547.2017/8.9, V.V. Dotsenko, I.V. Aksenova; project no. 4.1196.2017/4.6, N.A. Aksenov) and carried out using the equipment of Research Center “Diagnostics of Structure and Properties of Nanomaterials–Center for Collective Usage” and Center for Collective Usage “Ecological-Analytical Center” (universal identifier RFMEFI59317X0008) of Kuban State University.

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Authors and Affiliations

  1. Kuban State University, ul. Stavropol’skaya 149, Krasnodar, 350040, Russia

    I. A. Kotlova, F. A. Kolokolov & V. V. Dotsenko

  2. North-Caucasus Federal University, Stavropol, Russia

    V. V. Dotsenko, N. A. Aksenov & I. V. Aksenova

Authors
  1. I. A. Kotlova
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  2. F. A. Kolokolov
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  3. V. V. Dotsenko
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  4. N. A. Aksenov
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  5. I. V. Aksenova
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Corresponding author

Correspondence to I. A. Kotlova.

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No conflict of interest was declared by the authors.

Additional information

Russian Text © The Author(s), 2019, published in Zhurnal Obshchei Khimii, 2019, Vol. 89, No. 12, pp. 1901–1908.

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Kotlova, I.A., Kolokolov, F.A., Dotsenko, V.V. et al. Synthesis and Luminescent Properties of Eu3+, Gd3+, and Tb3+ Complexes with Quinoline-4-carboxylic Acids. Russ J Gen Chem 89, 2413–2419 (2019). https://doi.org/10.1134/S1070363219120144

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  • DOI: https://doi.org/10.1134/S1070363219120144

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