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Mechanically Activated Solid-Phase Reaction of Copper(I) Chloride with Sodium β-Diketonates: Formation of Metallic Copper Nanoparticles

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Abstract

Solid-phase reaction of copper(I) chloride with sodium β-diketonates under mechanical activation in a vibration ball mill involves disproportionation of CuCl with the formation of the corresponding copper(II) β-diketonate and highly reactive X-ray amorphous metallic copper nanoparticles. The effect of reaction conditions on the process and some properties of the activated mixtures have been studied.

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Funding

This study was financially supported by the Ministry of Education and Science within the framework of State contract (State registration no. 01201361869)..

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow oblast, Russia

    V. D. Makhaev, L. A. Petrova & Yu. M. Shulga

Authors
  1. V. D. Makhaev
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  2. L. A. Petrova
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  3. Yu. M. Shulga
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Corresponding author

Correspondence to V. D. Makhaev.

Additional information

Russian Text © The Author(s), 2019, published in Zhurnal Obshchei Khimii, 2019, Vol. 89, No. 7, pp. 1096–1100.

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Makhaev, V.D., Petrova, L.A. & Shulga, Y.M. Mechanically Activated Solid-Phase Reaction of Copper(I) Chloride with Sodium β-Diketonates: Formation of Metallic Copper Nanoparticles. Russ J Gen Chem 89, 1447–1450 (2019). https://doi.org/10.1134/S1070363219070156

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