Abstract
The reaction of methyl- and phenylphosphonic dichlorides with phenols in the presence of anhydrous magnesium chloride as catalyst or magnesium metal as precatalyst provides a simple, efficient, and practical method of synthesis of the corresponding aryl methyl- and phenylphosphonochloridates.
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Dedicated to the 110th anniversary of M.I. Kabachnik’s birth
Original Russian Text © E.I. Goryunov, I.B. Goryunova, G.N. Molchanova, I.Yu. Kudryavtsev, T.V. Baulina, A.A. Khodak, T.V. Strelkova, V.K. Brel, 2018, published in Zhurnal Obshchei Khimii, 2018, Vol. 88, No. 9, pp. 1426–1430.
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Goryunov, E.I., Goryunova, I.B., Molchanova, G.N. et al. Electrophilic Catalysis in the Synthesis of Aryl Methyl- and Phenylphosphonochloridates. Russ J Gen Chem 88, 1776–1779 (2018). https://doi.org/10.1134/S1070363218090025
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DOI: https://doi.org/10.1134/S1070363218090025