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Reactivity of Silver(I) Diethyldithiocarbamate and Ion-Polymeric Complexes {[Au(S2CNEt2)2][AgCl2]}n and {[Au(S2CNEt2)2]2[AgCl2]Cl·2H2O}n: Synthesis, Supramolecular Structures, and Thermal Behavior

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Abstract

New ion polymeric gold(III)–silver(I) complexes, {[Au(S2CNEt2)2][AgCl2]}n and {[Au(S2CNEt2)2]2[AgCl2]Cl·2H2O}n have been synthesized and characterized by X-ray diffraction data and IR spectra. The structure of the first complex is represented by [Au{S2CNEt2}2]+ complex cations and polymeric silver chloride anion ([AgCl2]–)n; the second complex consists of isomeric cations, linear [AgCl2]– anions, chloride ions, and water molecules. Gold cations are involved in zigzag (AuAuAu angle 99.06°) and linear polymeric chains via secondary Au···S bond pairs. Thermal decomposition of the complexes with regeneration of gold and silver has been studied by simultaneous thermal analysis (STA).

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Authors and Affiliations

  1. Institute of Geology and Nature Management, Far East Branch, Russian Academy of Sciences, per. Relochnyi 1, Blagoveshchensk, 675000, Russia

    E. V. Korneeva, O. V. Loseva & A. V. Ivanov

  2. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090, Russia

    A. I. Smolentsev

  3. Novosibirsk State University, ul. Pirogova 1, Novosibirsk, 630090, Russia

    A. I. Smolentsev

Authors
  1. E. V. Korneeva
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  2. O. V. Loseva
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  3. A. I. Smolentsev
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  4. A. V. Ivanov
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Correspondence to A. V. Ivanov.

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Original Russian Text © E.V. Korneeva, O.V. Loseva, A.I. Smolentsev, A.V. Ivanov, 2018, published in Zhurnal Obshchei Khimii, 2018, Vol. 88, No. 8, pp. 1361–1370.

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Korneeva, E.V., Loseva, O.V., Smolentsev, A.I. et al. Reactivity of Silver(I) Diethyldithiocarbamate and Ion-Polymeric Complexes {[Au(S2CNEt2)2][AgCl2]}n and {[Au(S2CNEt2)2]2[AgCl2]Cl·2H2O}n: Synthesis, Supramolecular Structures, and Thermal Behavior. Russ J Gen Chem 88, 1681–1689 (2018). https://doi.org/10.1134/S1070363218080200

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  • DOI: https://doi.org/10.1134/S1070363218080200

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