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Binding of gold(iii) with silver(i) dipropyldithiocarbamate: supramolecular self-assembly (role of secondary Au…S and Ag…S bonds) and thermal behavior of the ionic-polymer complex ([Au(S2CNPr2)2][AgCl2])n

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Abstract

The double ionic-polymer complex ([Au(S2CNPr2)2][AgCl2])n (1) was prepared as an individual fixation form of gold(III) from NaCl solutions with silver(I) dipropyldithiocarbamate and was characterized by single-crystal X-ray diffraction and 13C magic-angle spinning (MAS) NMR spectroscopy. The structure of 1 comprises two nonequivalent centrosymmetric complex cations [Au(S2CNPr2)2]+ (A and B) and the discrete linear anion [AgCl2]–. Gold(III) cations are linked by pairs of unsymmetrical secondary Au…S bonds to form linear supramolecular chains (…A…B…)n. Neighboring cations are additionally linked by [AgCl2]– anions via secondary Ag…S and Cl…S bonds, the anions being involved in the overall stabilization of the supramolecular structure. The cation–anion interactions lead to a distortion of the linear configuration of the [AgCl2]– anion. The character of thermolysis of 1 accompanied by quantitative regeneration of bound Au and Ag was established by simultaneous thermal analysis.

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Authors and Affiliations

  1. Institute of Geology and Nature Management, Far-Eastern Branch of the Russian Academy of Sciences, 1 Relochnyi per., 675000, Blagoveschensk, Russian Federation

    E. V. Korneeva & A. V. Ivanov

  2. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 prosp. Akad. Lavrentieva, 630090, Novosibirsk, Russian Federation

    A. I. Smolentsev

  3. Novosibirsk State University, 1 ul. Pirogova, 630090, Novosibirsk, Russian Federation

    A. I. Smolentsev

  4. Luleå University of Technology, SE-971 87, Luleå, Sweden

    O. N. Antzutkin

  5. University of Warwick, Coventry, CV4 7AL, United Kingdom

    O. N. Antzutkin

Authors
  1. E. V. Korneeva
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  2. A. I. Smolentsev
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  3. O. N. Antzutkin
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  4. A. V. Ivanov
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Correspondence to A. V. Ivanov.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 0040–0047, January, 2019.

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Korneeva, E.V., Smolentsev, A.I., Antzutkin, O.N. et al. Binding of gold(iii) with silver(i) dipropyldithiocarbamate: supramolecular self-assembly (role of secondary Au…S and Ag…S bonds) and thermal behavior of the ionic-polymer complex ([Au(S2CNPr2)2][AgCl2])n. Russ Chem Bull 68, 40–47 (2019). https://doi.org/10.1007/s11172-019-2413-7

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  • DOI: https://doi.org/10.1007/s11172-019-2413-7

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