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1-Phenyl-1-X-1-silacyclohexanes (X = MeO, OH, Me2N)

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Abstract

By the reaction of nucleophilic substitution of chlorine in 1-phenyl-1-chloro-1-silacyclohexane new 1-phenyl-1-X-1-silacyclohexanes (Х = МеО, ОН, Ме2N) have been synthesized and their stability with respect to the formation of (1,1′-phenyl-1,1′-silacyclohex-1-yl)disiloxane have been investigated.

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References

  1. Shainyan, B.A. and Kleinpeter, E., Tetrahedron, 2013, vol. 69, no. 29, p. 5927. doi 10. 1016/j.tet.2013.04.126

    Article  CAS  Google Scholar 

  2. Suslova, E.N. and Shainyan, B.A., Russ. J. Gen. Chem., 2016, vol. 86, no. 8, p. 1854. doi 10.1134/S1070363216080132

    Article  CAS  Google Scholar 

  3. Shainyan, B.A., Belyakov, A.V., Sigolaev, Y.F., Khramov, A.N., and Kleinpeter, E., J. Org. Chem., 2017, vol. 82, no. 1, p. 461. doi 10.1021/acs.joc.6b02538

    Article  CAS  Google Scholar 

  4. West, R., J. Am. Chem. Soc., 1954, vol. 76, no. 23, p. 6012. doi 10.1021/ja01652a035

    Article  CAS  Google Scholar 

  5. Nguyen, B.T. and Cartledge, F.K., J. Org. Chem., 1986, vol. 51, no. 12, p. 2206. doi 10.1021/jo00362a009

    Article  CAS  Google Scholar 

  6. Gudnason, P.I. and Arnason, I., Org. Lett., 2009, vol. 11, no. 9, p. 2015. doi 10.1021/ol900462z

    Article  CAS  Google Scholar 

  7. Kirpichenko, S.V., Kleinpeter, E., Ushakov, I.A., and Shainyan, B.A., J. Phys. Org. Chem., 2011, vol. 24, no. 4, p. 320. doi 10.1002/poc.1758

    Article  CAS  Google Scholar 

  8. Shainyan, B.A. and Kleinpeter, E., Tetrahedron, 2012, vol. 68, no. 1, p. 114. doi 10.1016/j.tet.2011.10.082

    Article  CAS  Google Scholar 

  9. Ortega, R., Sanchez-Quesada, J., Lorenz, D., Dolega, G., Karawajczyk, A., Sanz, M., Showell, G., and Giordanetto, F., Bioorg. Med. Chem., 2015, vol. 23, no. 11, p. 2716. doi 10. 1016/j.bmc.2015.01.046

    Article  CAS  Google Scholar 

  10. Chandrasekhar, V., Boomishankar, R., and Nagendran, S., Chem. Rev., 2004, vol. 104, no. 12, p. 5847. doi 10.1021/cr0306135

    Article  CAS  Google Scholar 

  11. George, P.D., Sommer, L.H., and Whitmore, F.C., J. Am. Chem. Soc., 1953, vol. 75, no. 7, p. 1585. doi 10.1021/ja01468a010.

    Article  CAS  Google Scholar 

  12. Cella, J.A. and Carpenter J.C., J. Organomet. Chem., 1994, vol. 480, nos. 1–2, p. 23. doi 10.1016/0022-328X (94)87098-5

    Article  CAS  Google Scholar 

  13. Lazareva, N.F. and Nikonov, A.Yu., Monatsh. Chem., 2015, vol. 146, no. 6, p. 983. doi 10.1007/s00706-014-1366-7

    Article  CAS  Google Scholar 

  14. Fessenden, R. and Fessenden, J.S., Chem. Rev., 1961, vol. 61, no. 4, p. 361. doi 10.1021/cr60212a002

    Article  CAS  Google Scholar 

  15. Showell, G.A., Barnes, M.J., Daiss, J.O., Mills, J.S., Montana, J.G., Tacke, R., and Warneck, J.B.H., Bioorg. Med. Chem. Lett., 2006, vol. 16, no. 9, p. 2555. doi 10.1016/j.bmcl.2005.12.062

    Article  CAS  Google Scholar 

  16. Nikonov, A.Yu., Sterkhova, I.V., and Lazareva, N.F., Russ. J. Gen. Chem., 2014, vol. 84, no. 5, p. 883. doi 10.1134/S107036321405017X

    Article  CAS  Google Scholar 

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Correspondence to B. A. Shainyan.

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Original Russian Text © Е.N. Suslova, B.А. Shainyan, 2017, published in Zhurnal Obshchei Khimii, 2017, Vol. 87, No. 7, pp. 1218–1221.

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Suslova, E.N., Shainyan, B.A. 1-Phenyl-1-X-1-silacyclohexanes (X = MeO, OH, Me2N). Russ J Gen Chem 87, 1645–1648 (2017). https://doi.org/10.1134/S1070363217070349

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  • DOI: https://doi.org/10.1134/S1070363217070349

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