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Fe-catalyzed synthesis of methyl-(2E,4Z)-deca-2,4-dienoate, a component of sex pheromones of Pityogenes chalcographus and Acanthoscelides obtectus

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Abstract

Stereoselective synthesis of methyl-(2E,4Z)-deca-2,4-dienoate, a component of sex pheromones of Pityogenes chalcographus and Acanthoscelides obtectus, was performed on the basis of Fe-catalyzed cross-coupling of methyl-(2E,4Z)-5-chloropenta-2,4-dienoate with n-pentylmagnesium bromide.

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Authors and Affiliations

  1. Ufa State Petroleum Technological University, ul. Kosmonavtov 1, Ufa, 450062, Russia

    R. N. Shakhmaev, A. Sh. Sunagatullina, D. A. Akimova & V. V. Zorin

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  1. R. N. Shakhmaev
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  2. A. Sh. Sunagatullina
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  3. D. A. Akimova
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  4. V. V. Zorin
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Correspondence to R. N. Shakhmaev.

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Original Russian Text © R.N. Shakhmaev, А.Sh. Sunagatullina, D.А. Akimova, V.V. Zorin, 2017, published in Zhurnal Obshchei Khimii, 2017, Vol. 87, No. 7, pp. 1211–1213.

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Shakhmaev, R.N., Sunagatullina, A.S., Akimova, D.A. et al. Fe-catalyzed synthesis of methyl-(2E,4Z)-deca-2,4-dienoate, a component of sex pheromones of Pityogenes chalcographus and Acanthoscelides obtectus . Russ J Gen Chem 87, 1638–1640 (2017). https://doi.org/10.1134/S1070363217070325

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  • DOI: https://doi.org/10.1134/S1070363217070325

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