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(4-Methoxyphenyl)amine and its derivatives in the synthesis of O-silylurethanes, ureas, and formamides

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Abstract

Reactions of (4-methoxyphenyl)amine and its trimethylsilyl derivative with organosilicon isocyanates and phenylisocyanate have been studied. (4-Methoxyphenyl)formamide was first synthesized by the reaction of (4-methoxyphenyl)amine with ethyl formate. The structure of trimethylsilyl(4-methoxyphenyl)-carbamate and N-(4-methoxyphenyl)formamide was determined by X-ray diffraction (XRD) analysis.

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Correspondence to L. O. Belova.

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Original Russian Text © L.O. Belova, M.V. Pletneva, N.A. Golub, A.A. Korlyukov, A.D. Kirilin, A.V. Petrogradskii, 2017, published in Zhurnal Obshchei Khimii, 2017, Vol. 87, No. 7, pp. 1138–1142.

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Belova, L.O., Pletneva, M.V., Golub, N.A. et al. (4-Methoxyphenyl)amine and its derivatives in the synthesis of O-silylurethanes, ureas, and formamides. Russ J Gen Chem 87, 1531–1535 (2017). https://doi.org/10.1134/S1070363217070143

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  • DOI: https://doi.org/10.1134/S1070363217070143

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