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Complex amidoboranes M2[M1(NH2BH3)4] (M1 = Al, Ga; M2 = Li, Na, K, Rb, Cs)

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Abstract

Structural, spectral, and thermodynamic characteristics of complex amidoboranes M2[M1(NH2BH3)4] (M1 = Al, Ga; M2 = Li, Na, K, Rb, Cs) were calculated by the B3LYP/def2-SVPD quantum-chemical method. The procedure for the synthesis of these compounds by reactions of alkali metal amidoboranes with aluminum and gallium chlorides was suggested and experimentally tested. Reaction products were characterized by the NMR and IR spectroscopy and X-ray phase analysis.

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Authors and Affiliations

  1. St. Petersburg State University, Universitetskaya nab. 7–9, St. Petersburg, 199034, Russia

    A. M. Chernysheva, P. A. Shelyganov, I. V. Kazakov & A. Y. Timoshkin

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  1. A. M. Chernysheva
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  2. P. A. Shelyganov
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  3. I. V. Kazakov
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  4. A. Y. Timoshkin
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Correspondence to A. Y. Timoshkin.

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Original Russian Text © A.M. Chernysheva, P.A. Shelyganov, I.V. Kazakov, A.Y. Timoshkin, 2017, published in Zhurnal Obshchei Khimii, 2017, Vol. 87, No. 4, pp. 529–534.

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Chernysheva, A.M., Shelyganov, P.A., Kazakov, I.V. et al. Complex amidoboranes M2[M1(NH2BH3)4] (M1 = Al, Ga; M2 = Li, Na, K, Rb, Cs). Russ J Gen Chem 87, 665–669 (2017). https://doi.org/10.1134/S1070363217040016

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  • DOI: https://doi.org/10.1134/S1070363217040016

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