Russian Journal of General Chemistry

, Volume 87, Issue 1, pp 76–85

Synthesis, structure, and photoluminescence properties of N-{2-[5-(2-hydroxyphenylmethyleneamino)-1-alkylbenzimidazol-2-yl]phenyl}-4-methylbenzenesulfamides and their zinc complexes

  • Yu. V. Koshchienko
  • A. S. Burlov
  • N. I. Makarova
  • V. G. Vlasenko
  • S. A. Nikolaevskii
  • M. A. Kiskin
  • G. G. Alexandrov
  • D. A. Garnovskii
  • A. V. Metelitsa
  • V. I. Minkin
Article

Abstract

N-{2-[5-(2-Hydroxyphenylmethyleneamino)-1-alkylbenzimidazol-2-yl]phenyl}-4-methyl-benzenesulfamides (H2L) and their zinc complexes Zn2L2 were synthesized. The structure of the ligands and complexes was studied by IR, UV, 1Н NMR, X-ray absorption spectroscopy, and X-ray diffraction analysis. The complexes show green photoluminescence (λfl = 492 nm) with quantum yields φ = 0.07–0.17.

Keywords

benzimidazoles azomethines zinc complexes fluorescence X-ray absorption spectroscopy X-ray diffraction analysis 

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Copyright information

© Pleiades Publishing, Ltd. 2017

Authors and Affiliations

  • Yu. V. Koshchienko
    • 1
  • A. S. Burlov
    • 1
  • N. I. Makarova
    • 1
  • V. G. Vlasenko
    • 2
  • S. A. Nikolaevskii
    • 3
  • M. A. Kiskin
    • 3
  • G. G. Alexandrov
    • 3
  • D. A. Garnovskii
    • 4
  • A. V. Metelitsa
    • 1
  • V. I. Minkin
    • 1
  1. 1.Institute of Physical and Organic Chemistry of Southern Federal UniversityRostov-on-DonRussia
  2. 2.Institute of Physics of Southern Federal UniversityRostov-on-DonRussia
  3. 3.N.S. Kurnakov Institute of General and Inorganic ChemistryRussian Academy of SciencesMoscowRussia
  4. 4.Southern Scientific Centre Academy of SciencesRostov-on-DonRussia

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