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Synthesis, structure, and photoluminescence properties of 4-methyl-N-{2-([1-alkyl-2-[2-(p-tolylsulfonylamino)phenyl]benzimidazol-5-yl]iminomethyl)phenyl}benzenesulfonamides and their zinc complexes

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Abstract

4-Methyl-N-{2-([1-alkyl-2-[2-(p-tolylsulfonylamino)phenyl]benzimidazol-5-yl]iminomethyl)phenyl}-benzenesulfamides (H2L) and zinc complexes on their basis Zn2L2 have been synthesized. The structure of the ligands and complexes has been studied by IR, UV, 1Н NMR spectroscopy, X-ray absorption spectroscopy, and X-ray diffraction analysis.

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Authors and Affiliations

  1. Research Institute of Physical and Organic Chemistry, Southern Federal University, pr. Stachki 194/2, Rostov-on-Don, 344090, Russia

    Yu. V. Koshchienko, A. S. Burlov, N. I. Makarova & A. V. Metelitsa

  2. Research Institute of Physics, Southern Federal University, Rostov-on-Don, Russia

    V. G. Vlasenko

  3. Kurnakov Institute of General and Inorganic Chemistry of Russian Academy of Sciences, Moscow, Russia

    S. A. Nikolaevskii & M. A. Kiskin

  4. Southern Scientific Center of the Russian Academy of Sciences, Rostov-on-Don, Russia

    D. A. Garnovskii

  5. Russian Scientific Center “Kurchatov Institute,”, Moscow, Russia

    A. L. Trigub

Authors
  1. Yu. V. Koshchienko
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  2. A. S. Burlov
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  3. N. I. Makarova
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  4. V. G. Vlasenko
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  5. S. A. Nikolaevskii
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  6. M. A. Kiskin
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  7. D. A. Garnovskii
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  8. A. L. Trigub
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  9. A. V. Metelitsa
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Corresponding author

Correspondence to A. S. Burlov.

Additional information

Original Russian Text © Yu.V. Koshchienko, A.S. Burlov, N.I. Makarova, V.G. Vlasenko, S.A. Nikolaevskii, M.A. Kiskin, D.A. Garnovskii, A.L. Trigub, A.V. Metelitsa, 2017, published in Zhurnal Obshchei Khimii, 2017, Vol. 87, No. 4, pp. 631–638.

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Koshchienko, Y.V., Burlov, A.S., Makarova, N.I. et al. Synthesis, structure, and photoluminescence properties of 4-methyl-N-{2-([1-alkyl-2-[2-(p-tolylsulfonylamino)phenyl]benzimidazol-5-yl]iminomethyl)phenyl}benzenesulfonamides and their zinc complexes. Russ J Gen Chem 87, 764–772 (2017). https://doi.org/10.1134/S1070363217040168

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