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Novel organoantimony compounds [2,6-(OMe)2C6H3]3SbO and [2,6-(OMe)2C6H3]3Sb(NCO)2·0.5(CH3)2CO. Synthesis and structure

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Abstract

Novel organic compounds of antimony(V), tris(2,6-dimethoxyphenyl)antimony diisocyanate and oxide, have been prepared and studied by X-ray diffraction analysis. Antimony atoms in the diisocyanate molecule and in two symmetrically independent molecules of the oxide exhibit trigonal-bipyramidal and tetrahedral coordination, respectively.

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Authors and Affiliations

  1. Blagoveshchensk State Pedagogical University, ul. Lenina 104, Blagoveshchensk, 675000, Russia

    I. V. Egorova, V. V. Zhidkov, I. P. Grinishak & N. A. Rodionova

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  1. I. V. Egorova
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  2. V. V. Zhidkov
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  3. I. P. Grinishak
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  4. N. A. Rodionova
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Correspondence to I. V. Egorova.

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Original Russian Text © I.V. Egorova, V.V. Zhidkov, I.P. Grinishak, N.A. Rodionova, 2016, published in Zhurnal Obshchei Khimii, 2016, Vol. 86, No. 11, pp. 1841–1848.

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Egorova, I.V., Zhidkov, V.V., Grinishak, I.P. et al. Novel organoantimony compounds [2,6-(OMe)2C6H3]3SbO and [2,6-(OMe)2C6H3]3Sb(NCO)2·0.5(CH3)2CO. Synthesis and structure. Russ J Gen Chem 86, 2484–2491 (2016). https://doi.org/10.1134/S1070363216110141

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