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Tris(3-Fluorophenyl)antimony Derivatives (3-FC6H4)3Sb(OC6H3Br2-2,4)2, (3-FC6H4)3Sb(OC6Cl5-2,3,4,5,6)2, and (3-FC6H4)3Sb[OC(O)C6H4(NO2-2)]2: Synthesis and Structure

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Abstract

Tris(3-fluorophenyl)antimony bis(2,4-dibromophenoxide) (I), tris(3-fluorophenyl)antimony bis(pentachlorophenoxide) (II), and tris(3-fluorophenyl)antimony bis(2-nitrobenzoate) (III) have been synthesized by the reaction of tris(3-fluorophenyl)antimony with 2,4-dibromo- and 2,3,4,5,6-pentacholophenols and 2-nitrobenzoic acid in the presence of tert-butylperoxide. The antimony atoms in complexes I–III have a distorted trigonal bipyramidal coordination with aroxides (carboxyl) groups in axial positions (OSbO angles, 176.0(2)° (I), 174.89(7)° (II), 173.04(8)° (III); Sb–O distances, 2.057(5), 2.048(5) Å (I); 2.098(2), 2.106(2) Å (II); 2.120(6), 2.090(6) Å (III)).

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Authors and Affiliations

  1. National South Ural State Research University, Chelyabinsk, 454080, Russia

    V. V. Sharutin, O. K. Sharutina & A. N. Efremov

  2. Lobachevskii National Research State University, Nizhny Novgorod, 603950, Russia

    P. V. Andreev

Authors
  1. V. V. Sharutin
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  2. O. K. Sharutina
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  3. A. N. Efremov
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  4. P. V. Andreev
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Correspondence to V. V. Sharutin.

Additional information

Original Russian Text © V.V. Sharutin, O.K. Sharutina, A.N. Efremov, P.V. Andreev, 2018, published in Zhurnal Neorganicheskoi Khimii, 2018, Vol. 63, No. 2, pp. 164–169.

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Sharutin, V.V., Sharutina, O.K., Efremov, A.N. et al. Tris(3-Fluorophenyl)antimony Derivatives (3-FC6H4)3Sb(OC6H3Br2-2,4)2, (3-FC6H4)3Sb(OC6Cl5-2,3,4,5,6)2, and (3-FC6H4)3Sb[OC(O)C6H4(NO2-2)]2: Synthesis and Structure. Russ. J. Inorg. Chem. 63, 174–179 (2018). https://doi.org/10.1134/S0036023618020195

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  • DOI: https://doi.org/10.1134/S0036023618020195

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