Skip to main content
Log in

Formation of solid solutions of multiferroics in the Bi2O3–Nd2O3–Fe2O3 system

  • Published:
Russian Journal of General Chemistry Aims and scope Submit manuscript

Abstract

The sequence of phases appearance during the formation of Bi1–x Nd x FeO3 solid solutions in powder oxides mixtures of bismuth, neodymium, and iron has been determined. It has been shown that the closeness of the reaction mixture composition to that of the individual compound (BiFeO3 or NdFeO3) is essential for the realization of the series of phase transformations yielding solid solutions of multiferroics Bi1–x Nd x FeO3 as the final product, due to the prevalence of various interphase contacts in the starting reaction zone.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Kalinkin, A.N. and Skorikov, V.M., Russ. J. Inorg. Chem., 2010, vol. 55, no. 11, p. 1794. doi 110.1134/S0036023610110173

    Article  CAS  Google Scholar 

  2. Catalan, G. and Scott, J.F., Adv. Mater., 2009, vol. 21, p. 2463. doi 10.1002/adma.200802849

    Article  CAS  Google Scholar 

  3. Sosnowska, I., Peterlin-Neumaier, T., and Streichele, E., J. Phys. (C), 1982, vol. 15, p. 4835.

    CAS  Google Scholar 

  4. Mukherjee, J.L. and Wang, F.F.Y., J. Am. Ceram. Soc., 1971, vol. 54, no. 1, p. 31.

    Article  CAS  Google Scholar 

  5. Morozov, M.I., Lomanova, N.A., and Gusarov, V.V., Russ. J. Gen. Chem., 2003, vol. 73, no. 11, p. 1676. doi 10.1023/B:RUGC.0000018640.30953.70

    Article  CAS  Google Scholar 

  6. Bernardo, M.S., Jardiel, T., Peiteado, M., Caballero, A.C., and Villegas, M., J. Eur. Ceram. Soc., 2011, vol. 31, p. 3047. doi 10.1016/j.jeurceramsoc.2011.03.018

    Article  CAS  Google Scholar 

  7. Troyanchuk, I.O., Karpinsky, D.V., Bushinsky, M.V., Mantytskaya, O.S., Tereshko, N.V., and Shut, V.N., J. Am. Ceram. Soc., 2011, vol. 94, no. 12, p. 4502. doi 10.1111/j.1551-2916.2011. 04780.x

    Article  CAS  Google Scholar 

  8. Pikula, T., Dzik, J., Lisinska-Czekaj, A., Czekaj, D., and Jartych, E., J. Alloys Compd., 2014, vol. 6, p. 1. doi 10.1016/j.jallcom., 2014.04.011.

    Article  Google Scholar 

  9. Valant, M., Axelsson, A.-K., and Alford, N., Chem. Mater., 2007. Vol., 19, p. 5431. doi 10.1021/cm071730+

    Article  CAS  Google Scholar 

  10. He, X. and Gao, L., Ceram. Int., 2009, vol. 35, p. 975. doi 10.1016/j.ceramint.2008.04.013

    Article  CAS  Google Scholar 

  11. Lomanova, N.A. and Gusarov, V.V., Russ. J. Gen. Chem., 2013, vol. 83, no. 12, p. 2240. doi 10.1134/S1070363213120049.

    Article  Google Scholar 

  12. Lomanova, N.A. and Gusarov, V.V., Nanosystems: Physics, Chemistry, Mathematics, 2013, vol. 4, no. 5, p. 696.

    CAS  Google Scholar 

  13. Egorysheva, A.V., Kuvshinova, T.B., Volodin, V.D., Ellert, O.G., Efimov, N.N., Skorikov, V.M., Baranchikov, A.E., and Novotortsev, V.M., Inorg. Mater., 2013, vol. 49, no. 3, p. 310. doi 10.1134/S0020168513030035

    Article  CAS  Google Scholar 

  14. Perejon, A., Murafa, N., Sanchez-Jimenez, P.E., Criado, J.M., Subrt, J., Dianez, M.J., and Perez-Maqueda, L.A., J. Mater. Chem. (C), 2013, vol. 1, p. 3551. doi 10.1039/c3tc30446a

    Article  CAS  Google Scholar 

  15. Mathe, V.L., J. Magn. Magn. Mater., 2003, vol. 263, p. 344. doi 10.1016/S0304-8853(03)00112-4

    Article  CAS  Google Scholar 

  16. Mathe, V.L., Patankar, K.K., Patil, R.N., Lokhande, C.D., J. Magn. Magn. Mater., 2004, vol. 270, p. 380. doi 10.1016/j.jmmm.2003.09.004

    Article  CAS  Google Scholar 

  17. Mishra, R.K., Pradhan Dillip, K., Choudhary, R.N.P., and Banerjee, A., J. Magn. Magn. Mater., 2008, vol. 320, p. 2602. doi 10.1016/j.jmmm.2008.05.005

    Article  CAS  Google Scholar 

  18. Zhang, Y., Zhang, H., Yin, J., Zhang, H., Chen, J., Wang, W., and Wu, G., J. Magn. Magn. Mater., 2010, vol. 322, p. 2251. doi 10.1016/j.jmmm.2010.02.020

    Article  CAS  Google Scholar 

  19. Dzik, J., Bernard, H., Osinska, K., Lisinska-Czekaj, A., and Czekaj, D., Arch. Metallurgy Mater., 2011, vol. 56, no. 4, p. 1119. doi 10.2478/v10172-011-0125-6

    CAS  Google Scholar 

  20. Klyndyuk, A.I. and Chizhova, E.A., Glass Phys. Chem., 2015, vol. 41, no. 4, p. 421. doi 10.1134/S1087659615040100

    Article  CAS  Google Scholar 

  21. Iwahara, H., Esaka, T., Sato, T., and Takahashi, T., J. Solid State Chem., 1981, vol. 39, no. 2, p. 173. doi 10.1016/0022–4596(81)90328–5

    Article  CAS  Google Scholar 

  22. Palai, R., Katiyar, R.S., Schmid, H., Tissot, R., Clark, S.J., Robertson, J., Redfern, S.A.T., Catalan, G., ahnd Scott, J.F., Phys. Rev. (B), 2008, vol. 77, p. 014110. doi 10.1103/PhysRevB.77.014110

    Article  Google Scholar 

  23. Tugova, E.A., Klyndyuk, A.I., and Gusarov, V.V., Russ. J. Inorg. Chem., 2013, vol. 58, no. 7, p. 848. doi 10.1134/S0036023613070243

    Article  CAS  Google Scholar 

  24. Rubinchik, Ya.S., Soedineniya dvoinykh okislov redkozemel’nyh elementov (Compounds of Double Oxides of Rare Earth Elements), Minsk: Nauka i Tekhnika, 1974, p. 78.

    Google Scholar 

  25. Gusarov, V.V., Russ. J. Gen. Chem., 1997, vol. 67, no. 12, p. 1846.

    CAS  Google Scholar 

  26. Gusarov, V.V. and Suvorov, S.A., Russ. J. Appl. Chem., 1993, vol. 66, no. 3, p. 1529.

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to A. I. Klyndyuk.

Additional information

Original Russian Text © A.I. Klyndyuk, E.A. Tugova, O.N. Karpov, E.A. Chizhova, M.V. Tomkovich, V.M. Kononovich, 2016, published in Zhurnal Obshchei Khimii, 2016, Vol. 86, No. 10, pp. 1633–1639.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Klyndyuk, A.I., Tugova, E.A., Karpov, O.N. et al. Formation of solid solutions of multiferroics in the Bi2O3–Nd2O3–Fe2O3 system. Russ J Gen Chem 86, 2282–2287 (2016). https://doi.org/10.1134/S1070363216100066

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070363216100066

Keywords

Navigation