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Phenylsulfanyl(fluoro)-substituted phthalocyanine nickel complexes: Synthesis and self-association

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Abstract

By cross-condensation of 4,5-bis(phenylsulfanyl)phthalonitrile (A) with tetrafluorophthalo-nitrile (B) in the presence of nickel acetate nickel phthalocyanines of the type A4, A3B, ABAB, AABB were synthesized. Their spectral properties were studied and the propensity to association in benzene solutions was revealed. The concentration of complexes where the association becomes notable decreases with the increased dipole moment of the phthalocyanine.

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Authors and Affiliations

  1. Ivanovo State University of Chemistry and Technology, Sheremetevskii pr. 7, Ivanovo, 153000, Russia

    A. I. Koptyaev, N. E. Galanin & G. P. Shaposhnikov

Authors
  1. A. I. Koptyaev
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  2. N. E. Galanin
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  3. G. P. Shaposhnikov
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Correspondence to N. E. Galanin.

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Original Russian Text © A.I. Koptyaev, N.E. Galanin, G.P. Shaposhnikov, 2016, published in Zhurnal Obshchei Khimii, 2016, Vol. 86, No. 7, pp. 1203–1207.

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Koptyaev, A.I., Galanin, N.E. & Shaposhnikov, G.P. Phenylsulfanyl(fluoro)-substituted phthalocyanine nickel complexes: Synthesis and self-association. Russ J Gen Chem 86, 1679–1683 (2016). https://doi.org/10.1134/S1070363216070240

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  • DOI: https://doi.org/10.1134/S1070363216070240

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