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Synthesis and properties of double copper(I)–nickel(II) sulfite

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Abstract

Pourbaix diagrams of Cu–H2SO4–H2O and Ni–H2SO4–H2O systems have been refined, and stability regions of the sulfite phases have been determined. State diagrams of double copper(I)–copper(II) and copper(I)–nickel(II) sulfites have been constructed. Double copper(I)–nickel(II) sulfite has been isolated from aqueous solutions saturated with sulfur dioxide. The solutions at different ratios of the metals have been studied by spectrophotometry; the isolated double sulfite has been studied by X-ray diffraction, IR spectroscopy, dispersion analysis, and thermal analysis. Fundamentals of thermodynamic prognostication of the Cu2SO3·MSO3 double sulfites synthesis have been elaborated.

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Authors and Affiliations

  1. Murmansk State Technical University, ul. Sportivnaya 13, Murmansk, 183010, Russia

    E. A. Chalaya & M. V. Vasekha

  2. Chelyabinsk State University, Chelyabinsk, Russia

    A. G. Tyurin & A. I. Biryukov

Authors
  1. E. A. Chalaya
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  2. A. G. Tyurin
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  3. M. V. Vasekha
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  4. A. I. Biryukov
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Correspondence to M. V. Vasekha.

Additional information

Original Russian Text © E.A. Chalaya, A.G. Tyurin, M.V. Vasekha, A.I. Biryukov, 2016, published in Zhurnal Obshchei Khimii, 2016, Vol. 86, No. 7, pp. 1064–1071.

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Chalaya, E.A., Tyurin, A.G., Vasekha, M.V. et al. Synthesis and properties of double copper(I)–nickel(II) sulfite. Russ J Gen Chem 86, 1545–1551 (2016). https://doi.org/10.1134/S1070363216070021

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  • DOI: https://doi.org/10.1134/S1070363216070021

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