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Solubility of d-elements salts in organic and aqueous-organic solvents: III. Influence of intermolecular association on solubility of cadmium bromide and iodide

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Abstract

Solubility in the systems CdX2–H2O–Solv (X = Br, I; Solv = dimethyl sulfoxide, N,N-dimethyl acetamide, N,N-dimethyl formamide, and 1,4-dioxane) at 25°C was measured by the isothermal saturation method. A relation between the shape of the solubility isotherm and the structure of the binary solvent depending on its composition was found. Positions of solubility maxima and isotherms inflection points in the most cases correlate with destruction of intermolecular associates formed by solvent components.

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Authors and Affiliations

  1. St. Petersburg State University, Universitetskaya nab. 7–9, St. Petersburg, 199034, Russia

    N. A. Bogachev, A. O. Gorbunov, A. B. Nikolskii & M. Yu. Skripkin

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  1. N. A. Bogachev
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  2. A. O. Gorbunov
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  3. A. B. Nikolskii
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  4. M. Yu. Skripkin
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Corresponding author

Correspondence to N. A. Bogachev.

Additional information

Original Russian Text © N.A. Bogachev, A.O. Gorbunov, A.B. Nikolskii, M.Yu. Skripkin, 2016, published in Zhurnal Obshchei Khimii, 2016, Vol. 86, No. 7, pp. 1057–1063.

For communication II, see [1].

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Bogachev, N.A., Gorbunov, A.O., Nikolskii, A.B. et al. Solubility of d-elements salts in organic and aqueous-organic solvents: III. Influence of intermolecular association on solubility of cadmium bromide and iodide. Russ J Gen Chem 86, 1539–1544 (2016). https://doi.org/10.1134/S107036321607001X

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  • DOI: https://doi.org/10.1134/S107036321607001X

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