Skip to main content
SpringerLink
Log in

Colloidal stability and photophysical characteristics of luminesent silica nanoparticles modified with various nitrogen/oxygen-containing trialkoxysilanes

  • Published:
Russian Journal of General Chemistry Aims and scope Submit manuscript

Abstract

Surface modification of the luminescent silica nanoparticles doped with Tb(III)–p-sulfonatothiacalix[ 4]arene complex was carried out using a series of nitrogen/oxygen-containing trialkoxysilanes. It was found that groups capable of nonspecific interactions on the surface of the nanoparticles cause a significant decrease in their colloidal stability. The chromophore moieties in the modifiers were found to quench the luminescence of the nanoparticles. The surface modification of the nanoparticles is responsible for the change in the mechanism of luminescence quenching in the presence of copper(II) ions due to decreased accessibility of luminophores to the quencher.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Eliseeva, S.V. and Bünzli, J.-C.G., Chem. Soc. Rev., 2010, vol. 39, p. 189. DOI: 10.1039/b905604c.

    Article  CAS  Google Scholar 

  2. Heffern, M.C., Matosziuk, L.M., and Meade, T.J., Chem. Rev., 2014, vol. 114, p. 4496. DOI: 10.1021/cr400477t.

    Article  CAS  Google Scholar 

  3. Montalti, M., Prodi, L., Rampazzo, E., and Zaccheroni, N., Chem. Soc. Rev., 2014, vol. 43, p. 4243. DOI: 10.1039/C3CS60433K.

    Article  CAS  Google Scholar 

  4. Bünzli, J.-C.G., Coord. Chem. Rev., 2015, vols. 293–294, p. 19. DOI: 10.1016/j.ccr.2014.10.013.

    Article  Google Scholar 

  5. Lakowitz, J.R., Principles of Fluorescence Spectroscopy, New York: Springer, 1983. Translated under the title Osnovy fluorestsentnoi spektroskopii, Moscow: Mir, 1986, p.496.

    Book  Google Scholar 

  6. Mustafina, A., Fedorenko, S., Konovalova, O., Menshikova, A., Shevchenko, N., Soloveva, S., Konovalov, A., and Antipin, I., Langmuir, 2009, vol. 25, p. 3146. DOI: 10.1021/la8032572.

    Article  CAS  Google Scholar 

  7. Barja, B.C. and Aramendra, P.F., Photochem. Photobiol. Sci., 2008, vol. 7, p. 1391. DOI: 10.1039/B806071A.

    Article  CAS  Google Scholar 

  8. Turel, M., Duerkop, A., Yegorova, A., Scripinets, Y., Lobnik, A., and Samec, N., Anal. Chim. Acta, 2009, vol. 644, p. 53. DOI: 10.1016/j.aca.2009.04.011.

    Article  CAS  Google Scholar 

  9. Mukhametshina, A., Mustafina, A., Davydov, N., Fedorenko, S., Nizameev, I., Kadirov, M., Gorbatchuk, V., and Konovalov, A., Langmuir, 2015, vol. 31, p. 611. DOI: 10.1021/la503074p.

    Article  CAS  Google Scholar 

  10. Davydov, N., Mustafina, A., Burilov, V., Zvereva, E., Katsyuba, S., Vagapova, L., Konovalov, A., and Antipin, I., Chem. Phys. Chem., 2012, vol. 13, p. 3357. DOI: 10.1002/cphc.201200367.

    CAS  Google Scholar 

  11. Rostovtsev, V.V., Green, L.G., Fokin, V.V., and Sharpless, K.B., Angew. Chem. Int. Ed., 2002, vol. 41, p. 2596. DOI: 10.1002/1521-3773(20020715) 41:14<2596::AID-ANIE2596>3.0.CO;2-4.

    Article  CAS  Google Scholar 

  12. Sokolova, N. and Nenajdenko, V.G., RSC Adv., 2013, vol. 3, p. 16212. DOI: 10.1039/C3RA42482K.

    Article  CAS  Google Scholar 

  13. Armarego, W.L.F. and Chai, C.L.L., Purification of Laboratory Chemicals, New York: Elsevier, 2009, p.743.

    Google Scholar 

  14. Bürglová, K., Moitra, N., Hodacová, J., Cattoёn, X., and Man, M.W.C., J. Org. Chem., 2011, vol. 76, p. 7326. DOI: 10.1021/jo201484n.

    Article  Google Scholar 

  15. Tsuchida, K., US Patent 2013/66014 A1, 2013.

    Google Scholar 

  16. Wang, Q.-M. and Yan, B., J. Organomet. Chem., 2006, vol. 691, no. 2, p. 545. DOI: 10.1016/j.jorganchem. 2005.09.026.

    Article  CAS  Google Scholar 

  17. Iki, N., Fujimoto, T., and Miyano, S., Chem. Lett., 1998, vol. 27, p. 625. DOI: 10.1246/cl.1998.625.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Kazan (Volga Region) Federal University, ul. Kremlevskaya 18, Kazan, Tatarstan, 420008, Russia

    V. A. Burilov, A. T. Latypova & I. S. Antipin

  2. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, Tatarstan, Russia

    I. S. Antipin

  3. Kazan National Research Technological University, Kazan, Tatarstan, 420015, Russia

    R. A. Safiullin

Authors
  1. V. A. Burilov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. T. Latypova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. R. A. Safiullin
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. I. S. Antipin
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to V. A. Burilov.

Additional information

Original Russian Text © V.A. Burilov, A.T. Latypova, R.A. Safiullin, I.S. Antipin, 2016, published in Zhurnal Obshchei Khimii, 2016, Vol. 86, No. 3, pp. 523–529.

To the 100th Anniversary of A.N. Pudovik

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Burilov, V.A., Latypova, A.T., Safiullin, R.A. et al. Colloidal stability and photophysical characteristics of luminesent silica nanoparticles modified with various nitrogen/oxygen-containing trialkoxysilanes. Russ J Gen Chem 86, 661–667 (2016). https://doi.org/10.1134/S1070363216030245

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070363216030245

Keywords

Search

Navigation