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Synthesis and crystal structure of thiolate-bridged dinuclear platinum(II) complexes

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Abstract

Reactions of 2,2′-bipyridine platinum(II) complexes with 2-aminoethanethiol or 2,2′-disulfanediyldi-(ethan-1-amine) afforded new complexes [Pt2(μ-aet)(μ-aetH+)(bpy)2](NO3)4 · 2H2O and [Pt2(μ-aet)(μ-aetH+)· (bpy)2](NO3)4 ·5H2O and heteronuclear complex catena-[(bpy)Pt(μ-aet)Ag](NO3)2 · 3H2O (bpy = 2,2′-bipyridine, aet = 2-aminoethanethiol). All complexes were characterized by elemental analyses and X-ray diffraction data.

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Authors and Affiliations

  1. St. Petersburg State Institute of Technology, Moskovskii pr. 26, St. Petersburg, 190013, Russia

    R. V. Suezov, A. V. Eremin, N. L. Medvedskii & A. N. Belyaev

  2. St. Petersburg State University, Universitetskii pr. 26, St. Petersburg, 198504, Russia

    V. V. Gurzhii

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  1. R. V. Suezov
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  2. A. V. Eremin
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  3. V. V. Gurzhii
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  4. N. L. Medvedskii
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  5. A. N. Belyaev
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Correspondence to R. V. Suezov.

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Original Russian Text © R.V. Suezov, A.V. Eremin, V.V. Gurzhii, N.L. Medvedskii, A.N. Belyaev, 2015, published in Zhurnal Obshchei Khimii, 2015, Vol. 85, No. 12, pp. 2064–2071.

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Suezov, R.V., Eremin, A.V., Gurzhii, V.V. et al. Synthesis and crystal structure of thiolate-bridged dinuclear platinum(II) complexes. Russ J Gen Chem 85, 2793–2800 (2015). https://doi.org/10.1134/S1070363215120221

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  • DOI: https://doi.org/10.1134/S1070363215120221

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