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The influence of the polarizability effect on the activation parameters of reactions of organometallic compounds

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Abstract

The literature data on the substituent influence on the energy, enthalpy, entropy, and free energy of activation for 21 series of organometallic compounds reactions have been analyzed. The activation parameters were first established to depend not only on the classic inductive, resonance, and steric effects but also on the polarizability effect of the substituents (the ion-dipole interaction in the transition state). In certain cases, the polarizability effect has the dominant influence on the considered parameters.

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Authors and Affiliations

  1. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, ul. Tropinina 49, Nizhny Novgorod, 603950, Russia

    O. V. Kuznetsova, A. N. Egorochkin & N. M. Khamaletdinova

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  1. O. V. Kuznetsova
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  2. A. N. Egorochkin
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  3. N. M. Khamaletdinova
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Correspondence to O. V. Kuznetsova.

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Original Russian Text © O.V. Kuznetsova, A.N. Egorochkin, N.M. Khamaletdinova, 2015, published in Zhurnal Obshchei Khimii, 2015, Vol. 85, No. 11, pp. 1877–1889.

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Kuznetsova, O.V., Egorochkin, A.N. & Khamaletdinova, N.M. The influence of the polarizability effect on the activation parameters of reactions of organometallic compounds. Russ J Gen Chem 85, 2617–2628 (2015). https://doi.org/10.1134/S1070363215110195

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  • DOI: https://doi.org/10.1134/S1070363215110195

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