Abstract
Magnetic behavior of Bi3Nb1–x Mn x O7–δ solid solutions of cubic and tetragonal modifications has been examined in comparison. The magnetic susceptibility studies have revealed that paramagnetic manganese atoms in the solid solutions of cubic and tetragonal modification exist as Mn(III) and Mn(IV) monomers as well as exchange-bound dimers: Mn(III)OMn(III), Mn(IV)OMn(IV), and Mn(III)OMn(IV). The exchange parameters and the distribution of monomers and dimers in the solid solutions have been determined as function of the paramagnetic atoms fraction.
Similar content being viewed by others
References
Chezhina, N.V., Zhuk, N.A., and Lyutoev, V.P., Russ. J. Gen. Chem.,, 2015, vol. 85, no. 7, p. 1599.
Takahashi, T., Iwahara, H., and Esaka, T., J. Appl. Electrochem., 1977, vol. 7, no 4, p. 303.
Fung, K.Z., Chen, J., and Virkar, A.V., J. Am. Ceram. Soc., 1993, vol. 76, no 10, p. 2403.
Struzik, M., Liu, X., Abrahams, I., Krok, F., Malys, M., and Dygas, J.R., Solid State Ionics, 2012, vol. 218, p. 25.
Fang, J., Ma, J., Sun, Y., Liu, Z., and Gao, C., Solid State Sci., 2011, vol. 13, p. 1649.
Wu, W., Liang, S., Shen, L., Ding, Z., Zheng, H., Su, W., and Wu, L., J. Alloys Compd., 2012, vol. 520, p. 213.
Zhou, W., Jefferson, D.A., and Thomas, J.M., Solid State Chem., 1987, vol. 70, p. 129.
Ling, C.D., Withers, R.L., Schmid, S.S., and Thompson, J.G., Solid State Chem., 1998, vol. 119, p. 42.
Ling, C.D. and Johnson, M., Solid State Chem., 2004, vol. 177, p. 1838.
Castro, A., Aguado, E., Rojo, J.M., Herrero, P., Enjalbert, R., and Galy, J., Mater. Res. Bull., 1998, vol. 33, p. 31.
Tang, D. and Zhou, W., Solid State Chem., 1995, vol. 119, p. 311.
Abrahams, I., Krok, F., Wrobel, W., Kozanecka- Szmigiel, A., and Cham, S.C.M., Solid State Ionics., 2008, vol. 179, p. 2.
Abrahams, I., Krok, F., Kozanecka-Szmigiel, A., Cham, S.C.M., and Dygas, J.R., J. Power Sources, 2007, vol. 173, p. 788.
Abrahams, I., Krok, F., Chan, S.C.M., Wrobel, W., Kozanecka-Szmigiel, A., Luma A., and Dygas, J.R., J. Solid Electrochem., 2006, vol. 10, p. 569.
Leszczynska, M., Holdynski, M., Krok, F., Abrahams, I., Liu, X., and Wrobel, W., Solid State Ionics, 2010, vol. 181, p. 796.
Ling C.D., Solid State Chem., 1999, vol. 148, p. 380.
Wang, X.P., Corbel, G., Kodjikian, S., Fang, Q.F., and Lacorre, P., Solid State Chem., 2006, vol. 179, p. 3338.
Valant, M. and Suvorov, D., J. Am. Ceram. Soc., 2004, vol. 87, p. 1056.
Shannon, R.D., Acta Crystallogr. (A), 1976, vol. 32, p. 751.
Zhuk, N.A., Kozhina, I.I., and Piir, I.V., Vestnik SPbGU, Ser. 4, no. 3, p. 42.
Zhuk, N.A., Girut’, E.S., Popova, T.A., and Obedina, T.V., Izv. Komi Scient. Center of Ural branch of RAS, 2014, no. 1(17), p.10.
Chezhina, N.V., Korolev, D.A., Sukharzhevskii, S.M., and Glumov, O.V., Russ. J. Gen. Chem.,, 2010, vol. 80, no. 5, p. 913.
Chezhina, N.V. and Korolev, D.A., Solid State Ionics, 2012, vol. 225, p. 201.
Zhuk, N.A., Piir, I.V., and Chezhina, N.V., Russ. J. Gen. Chem.,, 2006, vol. 76, no. 11, p. 1705.
Zhuk, N.A., Piir, I.V., and Chezhina, N.V., Russ. J. Gen. Chem.,, 2006, vol. 76, no. 11, p. 1710.
Zhuk, N.A., Piir, I.V., and Chezhina, N.V., Russ. J. Gen. Chem.,, 2008, vol. 78, no. 3, p. 376.
Zhuk, N.A., Piir, I.V., and Chezhina, N.V., Russ. J. Gen. Chem.,, 2007, vol. 77, no. 2, p. 215.
Chezhina, N.V., Piir, I.V., and Zhuk, N.A., Russ. J. Gen. Chem.,, 2008, vol. 78, no. 6, p. 1135.
Chezhina, N.V., Piir, I.V., and Zhuk, N.A., Russ. J. Gen. Chem.,, 2014, vol. 84, no. 2, p. 185.
Kalinnikov, V.T. and Rakitin, Yu.V., Vvedenie v magnetokhimiyu. Metod staticheskoi magnitnoi vospriimchivosti v khimii (Introduction to Magnetochemistry. Method of Static Magnetic Susceptibility in Chemistry), Moscow: Nauka, 1980.
Аkselrud, L.G., Gryn, Y.N., and Zavalij, P.Yu,. Abstracts of Papers, 12 Eur. Crystallogr. Meet., 1985, p. 55.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © N.V. Chezhina, N.A. Zhuk, 2015, published in Zhurnal Obshchei Khimii, 2015, Vol. 85, No. 11, pp. 1777–1785.
Rights and permissions
About this article
Cite this article
Chezhina, N.V., Zhuk, N.A. Structure, magnetic, and electrical properties of bismuth niobates doped with d-elements: XII. Magnetic behavior of Bi3Nb1–x Mn x O7–δ solid solutions. Russ J Gen Chem 85, 2520–2527 (2015). https://doi.org/10.1134/S1070363215110043
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1070363215110043