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Formation of a gold/silver-containing composite

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Abstract

Preparation of the Au/Ag composite in the 1 : 1 water–ethanol mixture in the presence of poly-N-vinylpyrrolidone has been optimized; the so prepared composite is applicable in the absorption spectroscopy based on the effect of plasmon resonance energy transfer. Of the studied cationic, anionic, and non-ionic polymer, only the 340 kDa poly-N-vinylpyrrolidone induced the formation of a monodisperse Au/Ag sol with the average hydrodynamic diameter of the particles of ≈73 nm. The composite structure built of the polymer core covered with the Au/Ag nanoparticles has likely formed. The prepared composite binds both anionic and cationic metal porphyrins preserving the efficient transfer of the plasmon resonance energy.

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Authors and Affiliations

  1. Institute of New Materials Chemistry, National Academy of Sciences of Belarus, ul. F. Skoriny 36, Minsk, 2200141, Belarus

    A. N. Eryomin, A. V. Abakshonok & V. E. Agabekov

  2. Stepanov Institute of Physics, National Academy of Sciences of Belarus, Minsk, Belarus

    A. Yu. Panarin & S. N. Terekhov

Authors
  1. A. N. Eryomin
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  2. A. V. Abakshonok
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  3. V. E. Agabekov
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  4. A. Yu. Panarin
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  5. S. N. Terekhov
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Correspondence to A. N. Eryomin.

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Original Russian Text © A.N. Eryomin, A.V. Abakshonok, V.E. Agabekov, A.Yu. Panarin, S.N. Terekhov, 2015, published in Zhurnal Obshchei Khimii, 2015, Vol. 85, No. 10, pp. 1620–1629.

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Eryomin, A.N., Abakshonok, A.V., Agabekov, V.E. et al. Formation of a gold/silver-containing composite. Russ J Gen Chem 85, 2252–2261 (2015). https://doi.org/10.1134/S1070363215100060

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  • DOI: https://doi.org/10.1134/S1070363215100060

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