Abstract
Alkaline hydrolysis of triphenylphosphonium salts containing 4-S-, N-, and O-substituted buta-1,3-diene group has been studied. 4-S-substituted phosphonium salts are hydrolyzed with formation of the corresponding diphenyl-1-phenyl-4-alkylsulfanylphosphoryl compounds, the products of anionotropic migration of the phenyl group. Under the same conditions, the 4-N- and O-substituted buta-1,3-diene phosphonium salts form triphenylphosphine oxide as the major product along minor diphenyl-4-N- or diphenyl-4-O-substituted buta-1,3-diene phosphine oxides.
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Ovakimyan, M.Zh., Gasparyan, G.Ts., Bichakhchyan, A.S., Pogosyan, A.S., Kinoyan, F.S., Tamazyan, R.A., and Aivasyan, A.G., Russ. J. Gen. Chem., 2014, vol. 84, no. 3, p. 496. DOI: 10.1134/S1070363214031141.
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Movsisyan, M.L., Russ. J. Gen. Chem., 2014, vol. 84, no. 3, p. 496. DOI: 10.1134/S1070363211030297.
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Original Russian Text © M.Zh. Ovakimyan, G.Ts. Gasparyan, A.S. Bichakhchyan, 2015, published in Zhurnal Obshchei Khimii, 2015, Vol. 85, No. 5, pp. 791–795.
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Ovakimyan, M.Z., Gasparyan, G.T. & Bichakhchyan, A.S. Special features of alkaline hydrolysis of 4-substituted buta-1,3-dienetriphenylphosphonium salts. Russ J Gen Chem 85, 1088–1092 (2015). https://doi.org/10.1134/S1070363215050151
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DOI: https://doi.org/10.1134/S1070363215050151