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Study of the metal-exchange reaction between Cd(II) octa(4-bromophenyl)tetraazaporphyrinate and cobalt chloride in organic solvents

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Abstract

The metal-exchange reaction between Cd(II) octa(4-bromophenyl)tetraazaporphyrinate and cobalt chloride in dimethylformamide and dimethyl sulfoxide was studied by spectrophotometry. Kinetic parameters of the metal-exchange reaction were determined. A possible stoichiometric mechanism of the reaction was proposed. Cobalt(III) octa(4-bromophenyl)tetraazaporphyrinate was synthesized and characterized.

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References

  1. Porfiriny: spektroskopiya, elektrokhimiya, primenenie (Porphyrins: Spectroscopy, Electrochemistry, Application), N.S. Enikolopyan, N.S., Ed., Moscow: Nauka, 1987.

    Google Scholar 

  2. Porphyrin Handbook, Smith, K., Kadish, K., and Guillard, R., Eds., New York: Academic, 2000, vol. 3, p. 129.

    Google Scholar 

  3. Krestov, G.A. and Berezin, B.D., Osnovnye ponyatiya sovremennoy khimii (Fumdamentals of Modern Chemistry), Leningrad: Khimiya, 1986.

    Google Scholar 

  4. Berezin, B.D., Zvezdina, S.V., and Berezin, M.B., Russ. J. Gen. Chem., 2013, vol. 83, no. 7, p. S. 1410. DOI: 10.1134/S1070363213070189.

    Article  CAS  Google Scholar 

  5. Zvezdina, S.V., Mal’tseva, O.V., Chizhova, N.V., and Mamardashvili, N.Zh., Abstracts of Papers, XXXI Nauchnaya sessiya Rossiiskogo seminara po khimii porfirinov i ikh analogov (XXXI Scientific Session of the Russian Seminar for the Chemistry of Porphyrins and Their Analogs), Ivanovo, 2014, p. 55.

    Google Scholar 

  6. Drobysheva, A.N., Karmanova, L.P., and Berezin, B.D., Zh. Fiz. Khim., 1977, vol. 57, no. 6, p. 1344.

    Google Scholar 

  7. Entelis, S.G. and Tiger, R.P., Kinetika reaktsii v zhidkoi faze (Kinetics of Liquid-Phase Reactions), Moscow: Khimiya, 1973.

    Google Scholar 

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Authors and Affiliations

  1. Krestov Institute of Solution Chemistry, Russian Academy of Sciences, ul. Akademicheskaya 1, Ivanovo, 153045, Russia

    S. V. Zvezdina, N. V. Chizhova & N. Zh. Mamardashvili

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  1. S. V. Zvezdina
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  2. N. V. Chizhova
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  3. N. Zh. Mamardashvili
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Correspondence to S. V. Zvezdina.

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Original Russian Text © S.V. Zvezdina, N.V. Chizhova, N.Zh. Mamardashvili, 2015, published in Zhurnal Obshchei Khimii, 2015, Vol. 85, No. 4, pp. 671–674.

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Zvezdina, S.V., Chizhova, N.V. & Mamardashvili, N.Z. Study of the metal-exchange reaction between Cd(II) octa(4-bromophenyl)tetraazaporphyrinate and cobalt chloride in organic solvents. Russ J Gen Chem 85, 911–914 (2015). https://doi.org/10.1134/S1070363215040258

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  • DOI: https://doi.org/10.1134/S1070363215040258

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