Abstract
Metal exchange reaction of magnesium(II) octa(4-bromophenyl)tetraazaporphyrinate with copper and cobalt chlorides in dimethylformamide has been studied by spectrophotometry measurements. Kinetic parameters of the metal exchange reaction have been determined. Possible stoichiometric mechanism of the reaction was proposed.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Al’Ansari Jana Fuad, PhD Thesis, Moscow, 2010.
Zvezdina, S.V., Chizhova, N.C., and Mamardasvili, N.Zh., J. Porphyrins Phthalocyanines, 2014, vol. 18, p. 169. DOI: 10.1142/S1088424613501095.
Berezin, B.D., Koordinatsionnye soedineniya porfirinov i ftalotsianina (Coordination Compounds of Phthalocyanines), Moscow: Nauka, 1978.
Askarov, K.A., Berezin, B.D., and Evstigneeva, R.P., Porfiriny: struktura, svoistva, sintez (Porphyrins: Structure, Properties, Synthesis), Moscow: Nauka, 1985.
Zvezdina, S.V. and Mamardashvili, N.Zh., Book of Abstracts, International Conf. “Spectroscopy of Coordination Compounds,” Tuapse, 2013, p. 163.
Zvezdina, S.V. and Mamardashvili, N.Zh., Russ. J. Coord. Chem., 2012, vol. 38, no. 5, p. 319. DOI: 10.1134/S1070328412050120.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © S.V. Zvezdina, N.V. Chizhova, N.Zh. Mamardashvili, 2014, published in Zhurnal Obshchei Khimii, 2014, Vol. 84, No. 11, pp. 1891–1894.
Rights and permissions
About this article
Cite this article
Zvezdina, S.V., Chizhova, N.V. & Mamardashvili, N.Z. Metal exchange reaction of magnesium(II) octa(4-bromophenyl)tetraazaporphyrinate with copper and cobalt chlorides in dimethylformamide. Russ J Gen Chem 84, 2187–2190 (2014). https://doi.org/10.1134/S1070363214110231
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1070363214110231