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Composition and structure of the incombustible residue from thermal decomposition of the ionic liquid N-decylpyridinium tetrachloroferrate(III)

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Abstract

A low-temperature ionic liquid, N-decylpyridinium tetrachloroferrate(III), has been synthesized, and its thermal stability in air has been studied by thermogravimetry. Combustion of the organic part of this ionic liquid leaves a solid residue which has been studied by elemental analysis, X-ray powder diffraction, scanning electron microscopy, IR spectroscopy, and magnetometry. The incombustible residue has been identified as hematite (crystalline α-Fe2O3) which is a weak ferromagnetic at room temperature.

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Authors and Affiliations

  1. Tver State University, Sadovyi per. 35, Tver, 170002, Russia

    O. E. Zhuravlev, A. Yu. Karpenkov, D. Yu. Karpenkov & L. I. Voronchikhina

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  1. O. E. Zhuravlev
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  2. A. Yu. Karpenkov
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  3. D. Yu. Karpenkov
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  4. L. I. Voronchikhina
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Correspondence to O. E. Zhuravlev.

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Original Russian Text © O.E. Zhuravlev, A.Yu. Karpenkov, D.Yu. Karpenkov, L.I. Voronchikhina, 2015, published in Zhurnal Obshchei Khimii, 2015, Vol. 85, No. 4, pp. 641–647.

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Zhuravlev, O.E., Karpenkov, A.Y., Karpenkov, D.Y. et al. Composition and structure of the incombustible residue from thermal decomposition of the ionic liquid N-decylpyridinium tetrachloroferrate(III). Russ J Gen Chem 85, 882–888 (2015). https://doi.org/10.1134/S1070363215040209

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  • DOI: https://doi.org/10.1134/S1070363215040209

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