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Mesomorphic and dielectric properties of the systems based on nematic cyanobiphenyls

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Abstract

Nematic cyanobiphenyls have been modified with small amount of polar additives. Phase transition temperatures as a function of composition of the prepared mixtures have been determined by polarization thermomicrscopy. The dielectric constant as a function of temperature has been determined via dielcometry measurements, and the dielectric anisotropy of the studied mixtures has been revealed. Broadening of the mesophase existence temperature range and enhancement of the dielectric anisotropy of the nematic biphenyls upon addition of polar dopants results from the supramolecular self-assembly via hydrogen bonding.

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References

  1. Kirsch, P. and Bremer, M., Angew. Chem. Int. Eng., 2000, vol. 39, p. 4216. DOI: 10.1002/1521-3773 (20001201)39:23<4216:AID-ANIE 4216>3.0.CO;2-K.

    Article  CAS  Google Scholar 

  2. Pauluth, D. and Tarumi, K., J. Mater. Chem., 2004, vol. 14, p. 1219. DOI: 10.1039/B400135B.

    Article  CAS  Google Scholar 

  3. Goodby, J.W., Liq. Cryst., 2011, vol. 38, p. 1363. DOI: 10.1080/02678292.2011.614700.

    Article  CAS  Google Scholar 

  4. Jankowiak, A., Ringstrand, B., Januszko, A., Kaszynski, P., and Wand, M.D., Liq. Cryst, vol. 40, p. 605. DOI: 10.1080/02678292.2013.774064.

  5. Jiang, Y., Zhongwei, An., Chen, P., Chen, X., and Zheng, M., Liq. Cryst., 2012, vol. 39, p. 457. DOI: 10.1080/02678292.2011.653410.

    Article  CAS  Google Scholar 

  6. Pramanic, A., Das, B., Garbat, K., Urban, S., and Dabrowski, R., Liq. Cryst., 2013, vol. 40, p. 149. DOI: 10.1080/02678292.2012.735707.

    Article  Google Scholar 

  7. Gray, G.W. and Kelly, S.M., J. Mater. Chem., 1999, vol. 9, p. 2037. DOI: 10.1039/A902682G.

    Article  CAS  Google Scholar 

  8. Bogi, A. and Faetti, S., Liq. Cryst., 2001, vol. 28, p. 729. DOI: 10.1080/02678290010021589.

    Article  CAS  Google Scholar 

  9. Wu, Sh.-Ts., Appl. Phys. Lett., 1994, vol. 64, p. 2191. DOI: 10.1063/1.111669.

    Article  CAS  Google Scholar 

  10. Aziz, N., Kelly, S.M., Duffy, W., and Goulding, M., Liq. Cryst., 2009, vol. 36, p. 503. DOI: 10.1080/02678290903031643.

    Article  CAS  Google Scholar 

  11. Lynch, M.D. and Patrick, D.L., Nano Lett., 2002, vol. 2, p. 1197. DOI: 10.1021/nl025694j.

    Article  CAS  Google Scholar 

  12. Park, K.A., Lee, S.M., Lee, S.H., and Lee, Y.H., J. Phys. Chem. (C), 2007, vol. 111, p. 1620. DOI: 10.1021/jp0659960.

    Article  CAS  Google Scholar 

  13. Popa-Nita, V. and Kralj, S., J. Chem. Phys., 2010, vol. 132, p. 024902. DOI: 10.1063/1.3291078.

    Article  CAS  Google Scholar 

  14. Yakuphanoglu, F., Bilgin-Eran, B., Ocak, H., and Oweimreen, G.A., Physica (B), 2007, vol. 393, p. 270. DOI: 10.1016/j.physb.2007.01.013.

    Article  CAS  Google Scholar 

  15. Yakuphanoglu, F., Okutan, M., Köysal, O., and Keum, S.-R., Dyes and Pigments, 2008, vol. 76, p. 202. DOI: 10.1016/j.dyepig., 2006.08.022.

    Article  Google Scholar 

  16. Yakuphanoglu, F., Okutan, M., Koysal, O., Ahn, S.-M., and Keum, S.R., Dyes and Pigments, 2008, vol. 76, p. 721. DOI: 10.1016/j.dyepig.2007.01.017.

    Article  CAS  Google Scholar 

  17. Magdi, M.N., Fahmi, A.A., and Almllal, W.A., Mol. Cryst. Liq. Cryst., 2010, vol. 518, p. 109. DOI: 10.1080/15421400903568070.

    Article  Google Scholar 

  18. Alaasar, M., Tschierske, C., and Prehm, M., Liq. Cryst., 2011, vol. 38, p. 925. DOI: 10.1080/02678292.2011.587130.

    Article  CAS  Google Scholar 

  19. Magdi, M.N., Fahmi, A.A., Refaie, A.A., and Alaasar, M.A., Liq. Cryst., 2012, vol. 39, p. 47. DOI: 10.1080/02678292.2011.611262.

    Article  Google Scholar 

  20. Wang, Y., Xu, H., and Zhang, X., Adv. Mater., 2009, vol. 21, p. 2849. DOI: 10.1002/adma.200803276.

    Article  CAS  Google Scholar 

  21. Cho, Ch.M., Wang, X., Li, J.J., He, Ch., and Xu, J., Liq. Cryst., 2013, vol. 40, p. 185. DOI: 10.1080/02678292.2012.735708.

    Article  CAS  Google Scholar 

  22. Burmistrov, V.A., Alexandriysky, V.V., and Koifman, O.I., Liq. Cryst., 1992, vol. 12. P. 403. DOI: 10.1080/02678299208031057.

    Article  CAS  Google Scholar 

  23. Burmistrov, V.A., Alexandriysky, V.V., and Koifman, O.I., Liq. Cryst., 1995, vol. 18, p. 657. DOI: 10.1080/02678299508036671.

    Article  CAS  Google Scholar 

  24. Aleksandriyskiy, V.V., Novikov, I.V., Burmistrov, V.A., and Koifman, O.I., Zh. Fiz. Khim., 1992, vol. 66, p. 1688.

    Google Scholar 

  25. Alexandriiskaya, E.V., Kuvshinova, S.A., Novikov, I.V., Alexandriiskii, V.V., Tararykina, T.V., Maizlish, V.E., and Burmistrov, V.A., Russ. J. Phys. Chem. (A), 2008, vol. 82, p. 1211. DOI: 10.1134/S0036024408070285.

    Article  Google Scholar 

  26. Aleksandriyskiy, V.V., Kuvshinova, S.A., Novikov, I.V., and Burmistrov, V.A., Izv. Vuzov, Ser. Khim. Khim. Tekhnol., 2013, vol. 56, p. 88.

    Google Scholar 

  27. Aleksandriyskiy, V.V., Burmistrov, V.A., and Koifman, O.I., Vodorodnaya svyaz’ v termotropnykh zhidkikh kristallakh (Hydrogen Bond in Thermotropic Liquid Crystals), Moscow: KRASAND, 2013.

    Google Scholar 

  28. Kuvshinova, S.A., Zav’yalov, A.V., Burmistrov, V.A., Koifman, O.I., and Aleksandriyskiy, V.V., Russ. J. Org. Chem., 2004, vol. 40, no. 8, p. 1113. DOI: 10.1023/B:RUJO.0000045889.46816.0b.

    Article  CAS  Google Scholar 

  29. Gray, G.W., Hartley, J.B., and Jones, B., J. Chem. Soc., 1955, vol. 4, p. 1412. DOI: 10.1039/JR9550001412.

    Article  Google Scholar 

  30. Litov, K.M., Kuvshinova, S.A., Burmistrov, V.A., Aleksandriyskiy, V.V., Potemkina, O.V., and Koifman, O.I., Zhid. Kristally Ikh Prakt. Ispol’z., 2013, no. 2(44), p. 5.

    Google Scholar 

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Authors and Affiliations

  1. Research Institute of Macroheterocyclic Compounds, Ivanovo State University of Chemistry and Technology, Sheremetevskii pr. 7, Ivanovo, 153000, Russia

    S. A. Kuvshinova, I. V. Novikov, V. A. Burmistrov, V. V. Aleksandriiskii & O. I. Koifman

  2. Institute of Solutions Chemistry, Russian Academy of Sciences, Ivanovo, Russia

    V. A. Burmistrov, V. V. Aleksandriiskii & O. I. Koifman

Authors
  1. S. A. Kuvshinova
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  2. I. V. Novikov
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  3. V. A. Burmistrov
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  4. V. V. Aleksandriiskii
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  5. O. I. Koifman
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Correspondence to S. A. Kuvshinova.

Additional information

Original Russian Text © S.A. Kuvshinova, I.V. Novikov, V.A. Burmistrov, V.V. Aleksandriiskii, O.I. Koifman, 2015, published in Zhurnal Obshchei Khimii, 2015, Vol. 85, No. 4, pp. 582–587.

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Kuvshinova, S.A., Novikov, I.V., Burmistrov, V.A. et al. Mesomorphic and dielectric properties of the systems based on nematic cyanobiphenyls. Russ J Gen Chem 85, 827–832 (2015). https://doi.org/10.1134/S107036321504009X

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  • DOI: https://doi.org/10.1134/S107036321504009X

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