Mesogenic 4-pentyl-4′-cyanobiphenyl (5CB) is a commonly used dielectric material for display devices and liquid crystal biosensors. A small concentration of ZnO nanoparticles was dispersed in 5CB nematic liquid crystals by the chemical precipitation method. The phase changes, phase retardation, and transition temperature of the prepared samples were studied by polarizing optical microscopy (POM) and differential scanning calorimetry analysis. The dielectric properties were measured by dielectric spectroscopy, which was performed within the frequency range from 1 Hz to 10 MHz. A novel phase was identified and confirmed by the dielectric parameters in dispersed ZnO 5CB (N5CB). Specifically, the temperature dependence of relaxation times was estimated for both the samples, which strengthen the POM studies and the influence of nanoparticles on the lattice arrangement. The temperature dependence and the dispersion effect of ZnO nanoparticles on the dielectric constant and dielectric losses were also studied. The sensitivity of mesogenic phases to external forces was confirmed through the present work. From all these results, it has been concluded that N5CB finds potential application in the preparation of fast switching devices.
Similar content being viewed by others
References
A. Achour, R. L. Porto, M. Akram Soussou, M. Islam, M. Boujtita, K. Ait, A. Djouadi, and T. Brousse, J. Power Sour., 300, 525–532 (2015).
X. Wang and P. See Lee, J. Mater. Chem. A, 3, 21706–21712 (2015).
Q. Ke and J. Wang, J. Materiomics, 2, 37–54 (2016).
S. Sampath, D. D. Sarma, and A. K. Shukla, ACS Energy Lett., 1, 1162–1164 (2016).
O. Muntesharia, J. Lauc, A. Krishnana, B. Dunnc, and L. Pilon, J. Power Sour., 374, 257–268 (2018).
A. Armutlulu, L. A. Bottomley, S. A. Bidstrup Allen, and M. G. Allen, Chem. Electrochem., 2, 236–245 (2014).
L. N. Jin, F. Shao, C. Jin, J. N. Zhang, P. Liu, M. X. Guo, and S. W. Bian, Electrochim. Acta, 249, 387–394 (2017).
S. Sreehari Sastry, S. Salma Begum, T. Vindhya Kumari, V. R. K. Murthy, and S. T. Ha, Asian J. Chem., 9, 2462–2471 (2012).
K. V. Surya Narayana Raju, S. Salma Begum, B. Dharma Sagar, and S. Babu, Rasayan J. Chem., 10, 37–45 (2017).
A. K. Srivastava, A. K. Misra, P. B. Chand, R. Manohar, and J. P. Shukla, Phys. Lett. A, 37, 490–498 (2007).
R. Manohar, S. P. Yadav, A. K. Srivastava, A. K. Misra, K. K. Pandey, P. K. Sharma, and A. C. Pandey, Jpn. J. Appl. Phys., 48, 101501–101506 (2009).
J. L. Gomez and O. Tigli, J. Mater. Sci., 48, No. 2, 612–624 (2013).
M. Chaari and A. Matoussi, Phys. B Condens. Mater., 407, 3441–3447 (2012).
P. G. Cummins, D. A. Dunmur, and D. A. Laidler, J. Mol. Cryst. Liq. Cryst., 30, 109–123 (1975).
A. Bogi and S. Faetti, J. Liq. Cryst., 28, 729–739 (2001).
V. A. Greanya, A. P. Malanoski, B. T. Weslowski, and M. S. Spector, Liq. Cryst., 32, 933–941 (2007).
S. I. Zhou, K. Neupane, Y. A. Nastishin, A. R. Baldwin, S. V. Shiyanovskii, O. D. Lavrentovich, and S. Sprunt, Liq. Cryst., 10, 6571–6581 (2017).
S. Mohyeddine, M. B. Pandey, and D. Revannasiddaiah, Phase Trans., 82, 11–18 (2009).
M. A. Bates and G. R. Luckhurst, Mol. Phys., 99, 1365–1371 (2001).
C. Wakai, A. Oleinikova, M. Ott, and H. Weingärtner, J. Phys. Chem. B, 109, 17028–17030 (2005).
A. Hourri, T. K. Bose, and J. Thoen, Phys. Rev. E, 63, 051702 (2001).
B. J. Thoen and T. K. Bose, Handbook of Low and High Dielectric Materials and their Applications, H. S. Nalwa Academic Press, San Diego, Vol. 1, pp. 501–561 (1999).
K. Rajendiran, K. Thananjeyan, and S. T. Yoganandham, Inorg. Chem. Comm., 117, 107954(1–7) (2020).
V. Tomar, T. F. Roberts, N. L. Abbott, J. P. Hernández-Ortiz, and J. J. de Pablo, Langmuir, 28, 6124–6131 (2012).
R. P. Pan, T. R. Tsai, C. Y. Chen, C. H. Wang, and C. L. Pan, Mol. Cryst. Liq. Cryst., 409, 137–144 (2004).
K. Tripathi, K. Mishra, S. M. Swadesh, K. Guptha, and R. Manohar, J. Mol. Struct., 1035, 371–377 (2013).
A. A. Ward, State of the Art — Dielectric Materials for Advanced Applications, National Research Centre, Egypt (2015).
M. M. Abdel-Aal, M. A. Ahmed, and L. Ateya, J. Phys. Soc. Jpn., 65, 3351–3356 (1996).
A. K. Jonscher, J. Phys. D: Appl. Phys., 32, 57–70 (1999).
C. C. Homes, S. M. Shapiro, and T. Vogt, Sciences, 293, 673–676 (2001).
A. J. Martin, G. Meier, and A. Saupe, Symp. Faraday Soc., 5, 119–133 (1971).
G. Meir and A. Saupe, Mol. Cryst. Liq. Cryst., 1, 515–525 (1996).
B. Bahadur, R. K. Sarna, and V. G. Bhide, Mol. Cryst. Liq. Cryst., 88, 151–165 (1982).
Author information
Authors and Affiliations
Corresponding author
Additional information
Abstract of article is published in Zhurnal Prikladnoi Spektroskopii, Vol. 89, No. 3, p. 437, May–June, 2022.
Rights and permissions
Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Raju, K.V.S.N., Begum, S.S., Madhav, B.T.P. et al. Optical and Dielectric Properties of ZnO Nematic Liquid Crystals Prepared by the Chemical Precipitation Method. J Appl Spectrosc 89, 602–611 (2022). https://doi.org/10.1007/s10812-022-01400-x
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10812-022-01400-x