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Reaction of alkyl splitting of 4-acetylamino-N-(3,5-di-tert-butyl-4-hydroxybenzyl)-benzenesulfonamide

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Abstract

Alkyl splitting of 4-acetylamino-N-(3,5-di-tert-butyl-4-hydroxybenzyl)benzenesulfonamide with alkali solution has been discovered, the reaction being uncommon for amides. The driving force of the process is the tendency of 3,5-di-tert-butyl-4-hydroxybenzyl derivatives to eliminate 2,6-di-tert-butyl-4-methylenecyclohexa-2,5-dienone in the presence of bases.

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Authors and Affiliations

  1. Kazan National Research Technological University, ul. K. Marksa 68, Kazan, Tatarstan, 420015, Russia

    Yu. N. Oludina, E. D. Ibatullina, S. V. Bukharov, G. N. Nugumanova, R. G. Tagasheva & R. Ya. Deberdeev

Authors
  1. Yu. N. Oludina
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  2. E. D. Ibatullina
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  3. S. V. Bukharov
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  4. G. N. Nugumanova
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  5. R. G. Tagasheva
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  6. R. Ya. Deberdeev
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Corresponding author

Correspondence to G. N. Nugumanova.

Additional information

Original Russian Text © Yu.N. Oludina, E.D. Ibatullina, S.V. Bukharov, G.N. Nugumanova, R.G. Tagasheva, R.Ya. Deberdeev, 2015, published in Zhurnal Obshchei Khimii, 2015, Vol. 85, No. 2, pp. 209–212.

To the 80th Anniversary of B.I. Ionin

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Oludina, Y.N., Ibatullina, E.D., Bukharov, S.V. et al. Reaction of alkyl splitting of 4-acetylamino-N-(3,5-di-tert-butyl-4-hydroxybenzyl)-benzenesulfonamide. Russ J Gen Chem 85, 383–386 (2015). https://doi.org/10.1134/S1070363215020061

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  • DOI: https://doi.org/10.1134/S1070363215020061

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