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Determination of trace amounts of Russian toxic agent VX

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Abstract

Method was developed for detection of residual amounts of Russian toxic agent RVX on metallic surface. The method is based on RVX conversion into O-isobutyl ester of methylphosphonic acid fluoride on a filter impregnated with silver fluoride, followed by detection of the formed derivative using a flame photometer. The method sensitivity has been enhanced by application of a large volume injection (0.20 mL). The method allows determination of RVX levels corresponding to the sanitary regulations and is intended for control measures at the toxic agents elimination establishments and for determination of the Danger grade of metallic waste.

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References

  1. Williams, J.M., Rowland, B., Jeffery, M.T., Groenewold, G.S., Appelhans, A.D., Gresham, G.L., and Olson, J.E., Langmuir., 2005, vol. 21, no. 6, p. 2386.

    Article  CAS  Google Scholar 

  2. Evans, R.A., Smith, W.L., Nguyen, N.P., Crouse, K.L., Crouse, C.L., Norman, S.D., and Jakubowski, E.M., Anal. Chem., 2011, vol. 83, p. 1315.

    Article  CAS  Google Scholar 

  3. Fowler, W.K. and Smith, J.E., J. Chromatogr., 1989, vol. 478, p. 51.

    Article  CAS  Google Scholar 

  4. Standart MVI 031-04-222-07. Saratov, 2007.

  5. Standart MVI 031-02-125-05, Saratov, 2005.

  6. Standart MVI 031-09-325-2010, Moscow, 2010.

  7. Stan’kov, I.N., Sergeeva, A.A., Sitnikov, V.B., Morozova, O.T., Derevyagina, I.D., Mylova, S.N., and Shchukin, V.M., J. Analyt. Chem., 2008, vol. 63, no. 7, p. 668.

    Article  Google Scholar 

  8. Mol Hans, G.J., Janssen, Hans-Gerd, Cramers, C.A., J. High Resol. Chromatogr., 1995, vol. 18, p. 19.

    Article  Google Scholar 

  9. Standart MUK 4.1.37-2012.

  10. Standart MUK 4.1.39-2012.

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Correspondence to L. K. Gustyleva.

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Original Russian Text © L.K. Gustyleva, E.I. Savel’eva, 2014, published in Zhurnal Obshchei Khimii, 2014, Vol. 84, No. 10, pp. 1734–1741.

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Gustyleva, L.K., Savel’eva, E.I. Determination of trace amounts of Russian toxic agent VX. Russ J Gen Chem 84, 2009–2015 (2014). https://doi.org/10.1134/S1070363214100259

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  • DOI: https://doi.org/10.1134/S1070363214100259

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