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Conformational structure of N-(silylmethyl)anilines PhNHCH2SiMe n (OEt)3-n (n = 0–3)

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Abstract

As show the data of IR spectroscopy and quantum-chemical calculations (B3LYP/6-311+G**), N-(silylmethyl)anilines PhNHCH2SiMe n (OEt)3−n in inert media have an intramolecular hydrogen bond NH⋯OSi. N-[(Trimethylsilyl)methyl]aniline PhNHCH2SiMe3 in inert solvents exists as a mixture of two conformers close in energy.

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Authors and Affiliations

  1. Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, Irkutsk, 664033, Russia

    I. V. Sterkhova, I. M. Lazarev, A. Yu. Nikonov & N. F. Lazareva

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  1. I. V. Sterkhova
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  2. I. M. Lazarev
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  3. A. Yu. Nikonov
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  4. N. F. Lazareva
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Correspondence to N. F. Lazareva.

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Original Russian Text © I.V. Sterkhova, I.M. Lazarev, A.Yu. Nikonov, N.F. Lazareva, 2014, published in Zhurnal Obshchei Khimii, 2014, Vol. 84, No. 6, pp. 938–943.

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Sterkhova, I.V., Lazarev, I.M., Nikonov, A.Y. et al. Conformational structure of N-(silylmethyl)anilines PhNHCH2SiMe n (OEt)3-n (n = 0–3). Russ J Gen Chem 84, 1121–1125 (2014). https://doi.org/10.1134/S1070363214060115

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  • DOI: https://doi.org/10.1134/S1070363214060115

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