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Formation of 1,1,3-trimethyl-3-(4-methylphenyl)butyl hydroperoxide complex with tetrabutylammonium bromide

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Abstract

The interaction of 1,1,3-trimethyl-3-(4-methylphenyl)butyl peroxide with tetrabutylammonium bromide has been studied by means of 1H NMR spectroscopy. The complex formation between the reacting species has been confirmed, its equilibrium constant being K = (3.01±0.09) L/mol at 294 K.

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Authors and Affiliations

  1. Donetsk National University, ul. Universitetskaya 24, Donetsk, 83001, Ukraine

    N. A. Turovskij, E. V. Raksha & Yu. V. Berestneva

  2. Litvinenko Institute of Physico-Organic Chemistry and Coal Chemistry, National Academy of Sciences of Ukraine, Donetsk, Ukraine

    M. Yu. Zubritskij

Authors
  1. N. A. Turovskij
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  2. E. V. Raksha
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  3. Yu. V. Berestneva
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  4. M. Yu. Zubritskij
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Correspondence to N. A. Turovskij.

Additional information

Original Russian Text © N.A. Turovskij, E.V. Raksha, Yu.V. Berestneva, M.Yu. Zubritskij, 2014, published in Zhurnal Obshchei Khimii, 2014, Vol. 84, No. 1, pp. 18–19.

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Turovskij, N.A., Raksha, E.V., Berestneva, Y.V. et al. Formation of 1,1,3-trimethyl-3-(4-methylphenyl)butyl hydroperoxide complex with tetrabutylammonium bromide. Russ J Gen Chem 84, 16–17 (2014). https://doi.org/10.1134/S1070363214010046

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  • DOI: https://doi.org/10.1134/S1070363214010046

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