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Complex formation of hydroperoxides with Alk4NBr according to NMR spectroscopy data

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Abstract

The reactions of tert-butyl hydroperoxide and 1,1,3-trimethyl-3-(4-methylphenyl)butyl hydroperoxide with tetraalkylammonium bromides (Alk4NBr) in various solvents were studied by NMR spectroscopy. The formation of a complex between a hydroperoxide molecule and quaternary ammonium salt was experimentally proved. The equilibrium constants for hydroperoxide—Alk4NBr complex formation (K c) were determined. The influence of water on the parameters of the 1H NMR spectrum of tert-butyl hydroperoxide was studied.

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Authors and Affiliations

  1. Donetsk National University, 24 ul. Universitetskaya, 83001, Donetsk, Ukraine

    N. A. Turovskij, Yu. V. Berestneva & E. V. Raksha

  2. L. M. Litvinenko Institute of Physical Organic Chemistry and Coal Chemistry, National Academy of Sciences of Ukraine, 70 ul. R. Lyuksemburg, 83114, Donetsk, Ukraine

    I. A. Opeida & M. Yu. Zubritskij

Authors
  1. N. A. Turovskij
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  2. Yu. V. Berestneva
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  3. E. V. Raksha
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  4. I. A. Opeida
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  5. M. Yu. Zubritskij
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Correspondence to N. A. Turovskij.

Additional information

Based on the materials of the XXV Conference “Modern Chemical Physics” (September 20–October 1, 2013, Tuapse).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1717–1721, August, 2014.

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Turovskij, N.A., Berestneva, Y.V., Raksha, E.V. et al. Complex formation of hydroperoxides with Alk4NBr according to NMR spectroscopy data. Russ Chem Bull 63, 1717–1721 (2014). https://doi.org/10.1007/s11172-014-0658-8

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  • DOI: https://doi.org/10.1007/s11172-014-0658-8

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