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Coordination compounds of copper(II) with substituted 3-{[(2-hydroxyphenyl)methylidene]amino}propane-1,2-diols

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Abstract

3-{[(2-Hydroxyphenyl)methylidene]amino}propane-1,2-diol, its 5-chloro-,5-bromo-, 5-nitro-, 3-methoxy derivatives, and 3-{[(2-hydroxynaphthyl-1)methylidene]amino}propane-1,2-diol react with hydrates of copper(II) chloride, bromide and nitrate in ethanol to form coordination compounds Cu(L)X·nH2O. Template condensation reaction between 3-aminopropane-1,2-diol and 2,3-, 2,4- or 2,5-dihydroxybenzaldehyde in the presence of copper(II) nitrate trihydrate results in similar compounds Cu(L)NO3·nH2O. Structure of some of the condensation products was identified by X-ray analysis. Thermolysis of the substances obtained occurs through the dehydration step (70–90°C) and complete thermal decomposition (290–560°C).

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Authors and Affiliations

  1. Moldavian State University, Mateevici St. 60, Chisinau, 2009, Moldova

    A. P. Gulea, V. O. Graur & V. I. Tsapkov

  2. Institute of Applied Physics of the Academy of Sciences of Moldova, Chisinau, Moldova

    Yu. M. Chumakov

Authors
  1. A. P. Gulea
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  2. Yu. M. Chumakov
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  3. V. O. Graur
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  4. V. I. Tsapkov
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Corresponding author

Correspondence to V. I. Tsapkov.

Additional information

Original Russian Text © A.P. Gulea, Yu.M. Chumakov, V.O. Graur, V.I. Tsapkov, 2013, published in Zhurnal Obshchei Khimii, 2013, Vol. 83, No. 9, pp. 1440–1446.

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Gulea, A.P., Chumakov, Y.M., Graur, V.O. et al. Coordination compounds of copper(II) with substituted 3-{[(2-hydroxyphenyl)methylidene]amino}propane-1,2-diols. Russ J Gen Chem 83, 1666–1672 (2013). https://doi.org/10.1134/S1070363213090077

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  • DOI: https://doi.org/10.1134/S1070363213090077

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