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Ozone interaction with manganese acetate solution. Formation of H x MnO2·nH2O layers and microtubes based on them

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Abstract

We present the first study of Mn(II) cations interaction with ozone fed onto the air/aqueous manganese acetate solution boundary. In the reaction, the layer of H x MnO2·nH2O of birnessite structure has been formed at the surface. Subsequent ∼1–3 μm thick layers drying at air has led to their rolling up to form microtubes with diameter of 20–50 μm and up to 10 mm long.

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Authors and Affiliations

  1. St. Petersburg State University, Universitetskii pr. 26, St. Petersburg, 198504, Russia

    V. P. Tolstoi & L. B. Gulina

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  1. V. P. Tolstoi
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  2. L. B. Gulina
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Correspondence to V. P. Tolstoi.

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Original Russian Text © V.P. Tolstoi, L.B. Gulina, 2013, published in Zhurnal Obshchei Khimii, 2013, Vol. 83, No. 9, pp. 1409–1413.

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Tolstoi, V.P., Gulina, L.B. Ozone interaction with manganese acetate solution. Formation of H x MnO2·nH2O layers and microtubes based on them. Russ J Gen Chem 83, 1635–1639 (2013). https://doi.org/10.1134/S1070363213090016

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  • DOI: https://doi.org/10.1134/S1070363213090016

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