Skip to main content
SpringerLink
Log in

Kinetics of two-stage mechanochemical synthesis of calcium zirconate in CaCO3-ZrO2 system

  • Published:
Russian Journal of General Chemistry Aims and scope Submit manuscript

Abstract

Reaction of formation of calcium zirconate in CaCO3-ZrO3 system at 1:1 molar ratio is studied at 800, 850, and 900°C. Preliminary mechanoactivation of the reagents mixture in the centrifugal planetary mill was used. Obtained conversion data were analyzed using a macrokinetic model of two-stage mechanochemical synthesis applying the Jander and Zhuravlev-Lesokhin-Tempelman equations.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Heinicke, G., Tribochemistry, Berlin:, Akademie-Verlag, 1984.

    Google Scholar 

  2. Avvakumov, E.G., Mehanokhimicheskie metody aktivatsii khimicheskikh protsessov (Mechanical Methods of Activation of Chemical Processes), Novosibirsk:, Nauka, 1986.

    Google Scholar 

  3. Butyagin, P.Yu., Usp. Khim., 1994, vol. 63, no. 12, p. 1031.

    Article  CAS  Google Scholar 

  4. Boldyrev, V.V., Usp. Khim., 2006, vol. 75, no. 3, p. 203.

    Article  Google Scholar 

  5. Rusanov, A.I., Zh. Obshch. Khim., 2007, vol. 77, no. 3, p. 203.

    Google Scholar 

  6. Fundamental’nye osnovy mekhanicheskoi aktivatsii, mekhanosinteza i mekhanokhimicheskikh tekhnologii (Fundamental Bases of Mechanic Activation, Mechano-synthesis, and Mechanochemical Technologies), Avvakumov, E.G., Ed., Novosibirsk:, Sib. Otd. Ross. Akad. Nauk, 2009.

    Google Scholar 

  7. Kuz’mitch, Yu.V., Kolesnikova, I.G., Serba, V.I., and Freidin, B.M., Mekhanicheskoe legirovanie (Mechanical Alloying), Apatity:, Izd. Kol’skogo Nauchnogo Tsentra Ross. Akad. Nauk, 2004.

    Google Scholar 

  8. Kalinkin, A.M., Balyakin, K.V., and Kalinkina, E.V., Zh. Obshch. Khim., 2012, vol. 82, no. 11, p. 1761.

    Google Scholar 

  9. Marchev, V.M., Gospodinov, G.G., and StoJanov, D.G., Zh. Obshch. Khim., 1999, vol. 69, no. 3, p. 371.

    Google Scholar 

  10. Boldyrev, V.V., Kinetika i Kataliz, 1972, vol. 13, no. 6, p. 1411.

    CAS  Google Scholar 

  11. Lyakhov, N.Z. and Boldyrev, V.V., Izv. Sib. Otd. Akad. Nauk SSSR, Ser. Khim., 1982, no. 12, issue 5, p. 3.

    Google Scholar 

  12. Urakaev, F.Kh. and Boldyrev, V.V., Neorg. Mater., 1999, vol. 35, no. 2, p. 248.

    Google Scholar 

  13. Fundamental’nye osnovy mekhanicheskoi aktivatsii, mekhanosinteza i mekhanokhimicheskikh tekhnologii (Fundamental Bases of Mechanic Activation, Mechanosynthesis, and Mechanochemical Technologies), Avvakumov, E.G., Ed., Novosibirsk:, Sib. Otd. Ross. Akad. Nauk, 2009, p. 128.

    Google Scholar 

  14. Avvakumov, E.G., Khimiya v Inter. Ust. Razv., 1994, vol. 2, nos. 2–3, p. 541.

    Google Scholar 

  15. Gerasimov, K.B., Gusev, A.A., Kolpakov, V.V., and Ivanov, E.Yu., Sib. Khim. Zh., 1991, no. 3, p. 140.

    Google Scholar 

  16. Yokogawa, H., J. Nat. Chem. Lab. Ind., 1988, vol. 83, spec. issue, p. 27.

    Google Scholar 

  17. Kopylov, A.V., Avvakumov, E.G., Urakaev, F.Kh., Izv. Sib. Otdel. Akad. Nauk SSSR, Ser. Khim., 1979, no. 9, issue 4, p. 8.

    Google Scholar 

  18. Butyagin, P.Yu., Kolloid. Zh., 1997, vol. 59, no. 4, p. 460.

    Google Scholar 

  19. Tret’yakov, Yu.D., Putlyaev, V.I., Vvedenie v khimiyu tverdofaznykh materialov (Introduction in Chemistry of Solid Materials), Moscow:, Nauka, 2006.

    Google Scholar 

  20. Brandt, S., Analiz dannykh. Statsticheskie i vychislitel’nye metody dlya nauchnykh rabotnikov i inzhenerov (Analysis of Date. Statistical and Computational Methods for Scientists and Engineers), Moscow:, Mir, 2003.

    Google Scholar 

  21. Povarov, V.G. and Blyandur, E.P., Kinetika i Kataliz, 1999, vol. 40, no. 4, p. 520.

    Google Scholar 

  22. Tromans, D. and Meech, J.A., Miner. Eng., 2001, vol. 14, no. 11, p. 1359.

    Article  CAS  Google Scholar 

  23. Molodetsky, I., Navrotsky, A., Paskowitz, M.J., Leppert, V.I., Risbud, S.H., J. Non-Cryst. Solids, 2000, vol. 262, nos. 1–3, p. 106.

    Article  CAS  Google Scholar 

  24. Wang, C., Zinkevich, M., and Aldinger, F., CALPHAD, 2004, vol. 28, no. 3, p. 281.

    Article  CAS  Google Scholar 

  25. Ohlberg, S.M. and Strickler, D.W., J. Am. Ceram. Soc., 1962, vol. 45, no. 4, p. 170.

    Article  CAS  Google Scholar 

  26. Young, R.A., Wiles, D.B., J. Appl. Crystallogr., 1982, vol. 15, part 4, p. 430.

    Article  CAS  Google Scholar 

  27. Boldyrev, V.V., Eksperimental’nye metody v mekhanokhimii tverdykh neorganicheskikh veshchestv (Experimental Methods in Chemistry of Solid Inorganic Substances), Novosibirsk:, Nauka, Novosibirsk Department, 1983.

    Google Scholar 

  28. Zyryanov, V.V., Sysoev, V.F., Boldyrev, V.V., and Korosteleva, T.V., USSR Authors Certificate no. 1375328, Bull. Izobret., 1988, no. 7, p. 39.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials, Kola Science Center, Russian Academy of Sciences, Akademgorodok 26a, Murmansk oblast, Apatity, 184209, Russia

    A. M. Kalinkin, K. V. Balyakin & E. V. Kalinkina

Authors
  1. A. M. Kalinkin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. K. V. Balyakin
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. E. V. Kalinkina
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. M. Kalinkin.

Additional information

Original Russian Text © A.M. Kalinkin, K.V. Balyakin, E.V. Kalinkina, 2013, published in Zhurnal Obshchei Khimii, 2013, Vol. 83, No. 8, pp. 1247–1257.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kalinkin, A.M., Balyakin, K.V. & Kalinkina, E.V. Kinetics of two-stage mechanochemical synthesis of calcium zirconate in CaCO3-ZrO2 system. Russ J Gen Chem 83, 1482–1492 (2013). https://doi.org/10.1134/S1070363213080021

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070363213080021

Keywords

Search

Navigation