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Chloroarylation and thiocyanatoarylation of itaconic acid

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Abstract

Under conditions of Meerwein reaction and anionarylation the aryldiazonium salts and itaconic acid form 2-chloro(thiocyanato)-2-benzylbutanedioic acids as the chloro- and thiocyianatoarylation products. The reaction is not accompanied by the decarboxylation process and other transformations affecting the carboxy groups of itaconic acid.

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Correspondence to V. S. Baranovskii.

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Original Russian Text © V.S. Baranovskii, B.M. Petrushka, A.Yu. Fesak, B.D. Grishchuk, 2013, published in Zhurnal Obshchei Khimii, 2013, Vol. 83, No. 2, pp. 271–274.

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Baranovskii, V.S., Petrushka, B.M., Fesak, A.Y. et al. Chloroarylation and thiocyanatoarylation of itaconic acid. Russ J Gen Chem 83, 325–328 (2013). https://doi.org/10.1134/S1070363213020151

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  • DOI: https://doi.org/10.1134/S1070363213020151

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