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On the “negative effect of nucleophilic solvation” in monomolecular heterolysis

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Abstract

Critical analysis of the evidence for the operation of the “negative effect of nucleophilic solvation” in the monomolecular heterolysis reactions of organic compounds was performed. The existence of this effect is not proved.

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Authors and Affiliations

  1. Donetsk National University, Universitetskaya St. 24, Donetsk, 83055, Ukraine

    I. M. Serebryakov

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  1. I. M. Serebryakov
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Correspondence to I. M. Serebryakov.

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Original Russian Text © I.M. Serebryakov, 2013, published in Zhurnal Obshchei Khimii, 2013, Vol. 83, No. 1, pp. 35–41.

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Serebryakov, I.M. On the “negative effect of nucleophilic solvation” in monomolecular heterolysis. Russ J Gen Chem 83, 32–37 (2013). https://doi.org/10.1134/S1070363213010052

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  • DOI: https://doi.org/10.1134/S1070363213010052

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