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Crystal and molecular structure of diphenyliodonium diiodobromide

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Abstract

A new salt, diphenyliodonium diiodobromide [C12H10I+][BrI2 −], was synthesized, isolated as brown crystals, and studied by XRD. The structure of the diphenyliodonium diiodobromide consists of separate, nearly linear anions BrI2 −, and cations C12H10I+. In the crystal of the salt there are strong intermolecular anionanion (BrI2 −…I2Br−) and anion-cation (I2Br−…I+) interactions. The complexation in the system of organic cation bromide-elemental iodine was studied spectrophotometrically.

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Authors and Affiliations

  1. Southern Federal University, ul. Zorge 7, Rostov-on-Don, 344090, Russia

    M. S. Chernov’yants, I. V. Burykin & A. A. Rostovskaya

  2. Nesmeyanov Institute of Organoelemental Compounds, Russian Academy of Sciences, Moscow, Russia

    Z. A. Starikova

Authors
  1. M. S. Chernov’yants
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  2. I. V. Burykin
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  3. Z. A. Starikova
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  4. A. A. Rostovskaya
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Correspondence to M. S. Chernov’yants.

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Original Russian Text © M.S. Chernov’yants, I.V. Burykin, Z.A. Starikova, A.A. Rostovskaya, 2012, published in Zhurnal Obshchei Khimii, 2012, Vol. 82, No. 11, pp. 1852–1855.

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Chernov’yants, M.S., Burykin, I.V., Starikova, Z.A. et al. Crystal and molecular structure of diphenyliodonium diiodobromide. Russ J Gen Chem 82, 1842–1845 (2012). https://doi.org/10.1134/S1070363212110205

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  • DOI: https://doi.org/10.1134/S1070363212110205

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