Skip to main content
SpringerLink
Log in

Synthesis, transport and ionophore properties of α,ω-biphosphorylated azapodands: V. Acid-base properties of new phosphorylated azapodands and α,ω-diamines and their participation in the membrane transport of I–III groups metal ions

  • Published:
Russian Journal of General Chemistry Aims and scope Submit manuscript

Abstract

Acid-base properties of newly and previously synthesized phosphorylated azapodands and α,ω-diamines and their amine precursors were studied. We found that they differ in the same range as has been found previously for the other aminophosphoryl compounds. The investigation of the processes of passive membrane ion transport of a series of metals of I–III groups by these reactants showed with all diphosphoryl diamines higher values of the transfer flow of the ions Sc(III), Nd(III), and Sm(III), than the ions of alkali and alkaline earth metals. Under the conditions of active membrane transport the azapodand IV exhibits high efficiency in the ion transport of Sr(II) and Ba(II), while diphosphoryldiamine III exhibits effective transport of Nd(III) ions. The factors that determine the efficiency and selectivity of the membrane extraction of the I–III groups metal ions by these diphosphoryl diamines are discussed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Cherkasov, R.A., Vasil’ev, R.I., Garifzyanov, A.R., and Talan, A.S., Zh. Obshch. Khim., 2008, vol. 78, no. 6, p. 940.

    Google Scholar 

  2. Cherkasov, R.A., Garifzyanov, A.R., Evseeva, N.S, Nizamov, I.S., and Nizamov, I.D., Zh. Obshch. Khim., 2010, vol. 80, no. 1, p. 158.

    Google Scholar 

  3. Garifzyanov, A.R., Zakharov, S.V., Kryukov, S.V., Galkin, V.I., and Cherkasov, R.A., Zh. Obshch. Khim., 2005, vol. 75, no. 8, p. 1273.

    Google Scholar 

  4. Cherkasov, R.A., Garifzyanov, A.R., Zakharov, S.V., Vinokurov, A.I., and Galkin, V.I., Zh. Obshch. Khim., 2006, vol. 76, no. 3, p. 438.

    Google Scholar 

  5. Cherkasov, R.A., Garifzyanov, A.R., Leont’eva, S.V., Davletshin, R.R., and Koshkin, S.A., Zh. Obshch. Khim., 2010, vol. 80, no. 1, p. 156.

    Google Scholar 

  6. Cherkasov, R.A., Garifzyanov, A.R., Leont’eva, S.V., Davletshin, R.R., and Koshkin, S.A., Zh. Obshch. Khim., 2009, vol. 79, no. 12, p. 1973.

    Google Scholar 

  7. Cherkasov, R.A., Garifzyanov, A.R., Galeev, R.R., Kurnosova, N.V., Davletshin, R.R., and Zakharov, S.V., Zh. Obshch. Khim., 2011, vol. 81, no. 7, p. 1114.

    Google Scholar 

  8. Cherkasov, R.A., Garifzyanov, A.R., Bazanova, O.B., and Leont’eva, S.V., Zh. Obshch. Khim., 2011, vol. 81, no. 10, p. 1627.

    Google Scholar 

  9. Cherkasov, R.A., Garifzyanov, A.R., Bazanova, E.B., Davletshin, R.R., and Leont’eva, S.V., Zh. Obshch. Khim., 2012, vol. 82, no. 1, p. 36.

    Google Scholar 

  10. Garifzyanov, A.R., Shirshova, N.V., and Cherkasov, R.A., Zh. Obshch. Khim., 2005, vol. 75, no. 4, p. 575.

    Google Scholar 

  11. Garifzyanov, A.R., Zakharov, S.V., and Cherkasov, R.A., Zh. Obshch. Khim., 2005, vol. 75, no. 7, p. 1118.

    Google Scholar 

  12. Cherkasov, R.A., Garifzyanov, A.R., Krasnova, N.S., Cherkasov, A.R., and Talan, A.S., Zh. Obshch. Khim., 2006, vol. 76, no. 10, p. 1603.

    Google Scholar 

  13. Turanov, A.N., Karandashev, V.K., Sharova, E.V., Artyushin, O.I., and Odinets, I.L., Solvent Extraction and Ion Exchange, 2010, vol. 28, no. 5, p. 579.

    Article  CAS  Google Scholar 

  14. Sharova, E.V., Artyushin, O.I., Turanov, A.N., Karandashev, V.K., Meshkova, S.B., Topilova, Z.M., and Odinets, I.L., Cent. Eur. J. Chem., 2012, vol. 10, no. 1, p. 146.

    Article  CAS  Google Scholar 

  15. Turanov, A.N., Karandashev, V.K., and Baulin, V.E., Radiokhimiya, 2008, vol. 50, no. 3, p. 229.

    Google Scholar 

  16. Cherkasov, R.A., Talan, A.S., Tarasov, A.V., and Garifzyanov, A.R., Zh. Obshch. Khim., 2008, vol. 78, no. 7, p. 1093.

    Google Scholar 

  17. Cherkasov, R.A., Garifzyanov, A.R., Talan, A.S., Davletshin, R.R., and Kurnosova, N.V., Zh. Obshch. Khim., 2009, vol. 79, no. 9, p. 1480.

    Google Scholar 

  18. Cherkasov, R.A., Garifzyanov, A.R., Talan, A.S., Minnulina, L.I., Davletshin, R.R., and Sal’nikov, Yu.I., Zh. Obshch. Khim., 2008, vol. 78, no. 11, p. 1913.

    Google Scholar 

  19. Cherkasov, R.A., Garifzyanov, A.R., Kurnosova, N.V., Matveeva, E.V., and Odinets, I.L., Izv. Ross. Akad. Naul, Ser. Khim., 2012, no. 1, p. 171.

  20. Cherkasov, R.A., Garifzyanov, A.R., Devyatov, F.V., Kurnosova, N.V., Rakhmaeva, A.I., and Davletshin, R.R., Zh. Obshch. Khim., 2012, vol. 82, no. 9, p. 1435.

    Google Scholar 

  21. Mezhov, E.A., Ekstraktsiya aminami i solyami chetvertichnykh ammonievykh osnovanii. Spravochnik po ekstraktsii (Extraction with Amines and Quaternary Ammonium Bases. Handbook), Moscow: Atomizdat, 1977.

    Google Scholar 

  22. Ivakhno, S.Yu. and Yurtov, E.V., Itogi Nauki i Tekhn., VINITI, Ser. Neorgan. Khim., Moscow: VINITI, 1990, vol. 18.

    Google Scholar 

  23. Mulder, M., Basic Principles of Membrane Technology, Moscow: Mir, 1999.

    Google Scholar 

  24. Zanjanchi, M.A., Arvand, M., Islamnezhad, A., and Mahmoodi, N.O., Talanta, 2007, vol. 74, p. 125.

    Article  CAS  Google Scholar 

  25. Bartsch, R.A. and Way, J.D., ACS Symposium Series, Amer. Chem. Soc., 1996, p. 1.

  26. Zakharov, S.V., Nurazdanova, G.Kh., Garifzyanov, A.R., Galkin, V.I., and Cherkasov, R.A., Zh. Obshch. Khim., 2004, vol. 74, no. 6, p. 946.

    Google Scholar 

  27. Garifzyanov, A.R., Vasil’ev, R.I., and Cherkasov, R.A., Zh. Obshch. Khim., 2005, vol. 75, no. 2, p. 244.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Kazan Federal University, ul. Kremlevskaya 18, Kazan, Tatarstan, 420008, Russia

    A. R. Garifzyanov, R. R. Davletshin, N. V. Davletshina & R. A. Cherkasov

Authors
  1. A. R. Garifzyanov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. R. R. Davletshin
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. N. V. Davletshina
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. R. A. Cherkasov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to R. A. Cherkasov.

Additional information

Original Russian Text © A.R. Garifzyanov, R.R. Davletshin, N.V. Davletshina, R.A. Cherkasov, 2012, published in Zhurnal Obshchei Khimii, 2012, Vol. 82, No. 10, pp. 1619–1627.

For communication IV, see [1].

Rights and permissions

Reprints and permissions

About this article

Cite this article

Garifzyanov, A.R., Davletshin, R.R., Davletshina, N.V. et al. Synthesis, transport and ionophore properties of α,ω-biphosphorylated azapodands: V. Acid-base properties of new phosphorylated azapodands and α,ω-diamines and their participation in the membrane transport of I–III groups metal ions. Russ J Gen Chem 82, 1646–1653 (2012). https://doi.org/10.1134/S1070363212100039

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070363212100039

Keywords

Search

Navigation