Skip to main content
SpringerLink
Log in

Influence of acido ligands on the structure of copper dihalide solvates with dimethyl sulfoxide and N,N-dimethylformamide

  • Published:
Russian Journal of General Chemistry Aims and scope Submit manuscript

Abstract

Structures of copper dihalide solvates with dimethyl sulfoxide (DMSO) and N,N-dimethylformamide (DMF) were determined by XRD single crystal analysis. The existence of two DMSO solvates with CuBr2, but only one with CuCl2, was attributed to a lower Cu-Br bond strength in comparison with Cu-Cl, and, as a consequence, by its easier breaking to form a bond with a solvent molecule. Fundamentally different structures of CuX2·2DMF (X = Br, Cl) solvates are caused by different donor power of the acido ligands.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Surrey, A.R., Name Reactions in Organic Chemistry, New York: Academic Press, 1961.

    Google Scholar 

  2. Qiu, W. and Burton, D.J., Tetrahedron Lett., 1996, vol. 37, no. 16, p. 2745.

    Article  CAS  Google Scholar 

  3. Kinzhalov, M.A., Gareeva, F.R., Stepakova, L.V., Skripkin, M.Yu., and Stepakov, A.V., Abstracts of Papers, Mezhdunarodnaya konf. po organicheskoi khimii “Organicheskaya khimiya ot butlerova i bel’stteina do sovremennosti” (International Conf. on Organic Chemistry “Organic Chemistry from Butlerov and Beilstein up to the Present”), St. Petersburg, 2006, p. 516.

  4. Willett, R.D., Jardine, F.H., and Roberts, S.A., Inorg. Chim. Acta, 1977, vol. 25, p. 97.

    Article  CAS  Google Scholar 

  5. Desiraju, G.R., Chem. Commun., 2005, no. 24, p. 2995.

  6. Willet, R.D. and Chang, K., Inorg. Chim. Acta, 1970, vol. 4, p. 447.

    Article  Google Scholar 

  7. Efimov, A.I., Belorukova, L.P., Vasil’kova, I.V., and Chechev, V.P., Svoistva neorganicheskikh soedinenii (Properties of Inorganic Compounds), Leningrad, Khimiya, 1983.

    Google Scholar 

  8. Suzuki, H., Fukushima, N., Ishiguro, S., Masuda, H., and Ohtaki, H., Acta Cryst. C, 1991, vol. 47, p. 1838.

    Article  Google Scholar 

  9. X-RED version 1.09, X-SHAPE version 1.02, STOE and Cie GmbH, Darmstadt, 1997.

  10. Altomare, A., Burla, M.C., Camalli, M., Cascarano, G., Giacovazzo, C., Guagliardi, A., Moliterni, A.G.G., Polidori, G., and Spagna, R., SIR-97. A Program for Automatic Solution and Refinement of Crystal Structure, Trieste, Italy.

  11. Sheldrick, G.M., SHELX 97, University of Gottingen, Germany, 1997.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. St. Petersburg State University, Universitetskii pr. 26, St. Petersburg, 198904, Russia

    K. K. Spektor, G. L. Starova, Yu. M. Skripkin & L. V. Stepakova

Authors
  1. K. K. Spektor
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. G. L. Starova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Yu. M. Skripkin
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. L. V. Stepakova
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to G. L. Starova.

Additional information

Original Russian Text © K.K. Spektor, G.L. Starova, Yu.M. Skripkin, L.V. Stepakova, 2011, published in Zhurnal Obshchei Khimii, 2011, Vol. 81, No. 9, pp. 1432–1437.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Spektor, K.K., Starova, G.L., Skripkin, Y.M. et al. Influence of acido ligands on the structure of copper dihalide solvates with dimethyl sulfoxide and N,N-dimethylformamide. Russ J Gen Chem 81, 1772–1777 (2011). https://doi.org/10.1134/S1070363211090064

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070363211090064

Keywords

Search

Navigation