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Reaction of tris(2-hydroxyethyl)amine hydrochloride with zinc diacetate and bis(2-methylphenoxy)acetate

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Abstract

Reaction of tris(2-hydroxyethyl)amine hydrochloride Cl− N+H(CH2CH2OH)3 with zinc diacetate and bis(2-methylphenoxy)acetate in the molar ratio 2: 1 results in complexes 2[Cl− N+H(CH2CH2OH)3]· Zn (OCOR)2 (I, II) R= Me (I), 2-MeC6H4OCH2 (II), which contain two protatrane cations linked with zinc diacylate by two coordination bonds HO → Zn. Complexes I and II are also formed by the reaction of the corresponding tris(2-hydroxyethyl)amine hydrochloride acylate RCOO−N+H(CH2CH2OH)3 with ZnCl2. The structure of complexes I, II is proved by elemental analysis, IR and 1H, 13C, 15N NMR spectroscopy.

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References

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Authors and Affiliations

  1. Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, Irkutsk, 664033, Russia

    S. N. Adamovich, R. G. Mirskov, A. N. Mirskova & M. G. Voronkov

Authors
  1. S. N. Adamovich
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  2. R. G. Mirskov
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  3. A. N. Mirskova
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  4. M. G. Voronkov
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Corresponding author

Correspondence to R. G. Mirskov.

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Original Russian Text © S.N. Adamovich, R.G. Mirskov, A.N. Mirskova, M.G. Voronkov, 2010, published in Zhurnal Obshchei Khimii, 2010, Vol. 80, No. 10, pp. 1661–1662.

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Adamovich, S.N., Mirskov, R.G., Mirskova, A.N. et al. Reaction of tris(2-hydroxyethyl)amine hydrochloride with zinc diacetate and bis(2-methylphenoxy)acetate. Russ J Gen Chem 80, 1972–1973 (2010). https://doi.org/10.1134/S1070363210100154

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  • DOI: https://doi.org/10.1134/S1070363210100154

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