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Structure of complex bromides crystallizing in MBr2-NEt4Br-H2O systems (M = Cd, Cu, Co) at 25°C

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Abstract

The crystalline structures of four tetraethylammonium salts, [Et4N]CdBrP3, [Et4N]Cd2Br5, [Et4N]2CoBr4, and [Et4N]2CuBr4 were determined by X-ray analysis of their single crystals. The CdBr 2 − x x anions in the examined salts are linked to polymeric chains, and the coordination number of cadmium ion is 5 or 6. The d-metal ion in the copper and cobalt complexes has tetrahedral configuration, and the corresponding anions are discrete.

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Authors and Affiliations

  1. St. Petersburg State University, Universitetskii pr. 26, St. Petersburg, 198504, Russia

    G. L. Starova, M. Yu. Skripkin & I. M. Gusev

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  1. G. L. Starova
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  2. M. Yu. Skripkin
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  3. I. M. Gusev
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Correspondence to M. Yu. Skripkin.

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Original Russian Text © G.L. Starova, M.Yu. Skripkin, I.M. Gusev, 2010, published in Zhurnal Obshchei Khimii, 2010, Vol. 80, No. 7, pp. 1070–1075.

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Starova, G.L., Skripkin, M.Y. & Gusev, I.M. Structure of complex bromides crystallizing in MBr2-NEt4Br-H2O systems (M = Cd, Cu, Co) at 25°C. Russ J Gen Chem 80, 1236–1241 (2010). https://doi.org/10.1134/S1070363210070030

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  • DOI: https://doi.org/10.1134/S1070363210070030

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