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Thallium(III) oxide as an oxidative reagent in organic chemistry

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Abstract

Oxidative properties of thallium(III) oxide in various organic reactions were studied. Oxidative bromination of organic compounds in Tl2O3-KBr-trifluoroacetic acid system was carried out. New synthetic method for preparation of diphenylthallium salts from phenylhydrazine and thallium(III) oxide was developed.

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Authors and Affiliations

  1. Vavilov Saratov State Agricultural University, ul. Sokolovaya 335, Saratov, 410005, Russia

    I. F. Gun’kin

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  1. I. F. Gun’kin
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Correspondence to I. F. Gun’kin.

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Original Russian Text © I.F. Gun’kin, 2010, published in Zhurnal Obshchei Khimii, 2010, Vol. 80, No. 3, pp. 428–431.

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Gun’kin, I.F. Thallium(III) oxide as an oxidative reagent in organic chemistry. Russ J Gen Chem 80, 451–454 (2010). https://doi.org/10.1134/S1070363210030138

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  • DOI: https://doi.org/10.1134/S1070363210030138

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