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α-Nitro chalcones: Structure and reaction with pyrrole

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Abstract

According to the 1H NMR, IR, and electronic absorption spectra and X-ray diffraction data, 2-aryl-1-benzoyl-1-nitroethenes have E configuration with predominant s-cis conformation, where the nitro group lies in the plane of the double carbon-carbon bond, while the carbonyl group deviates from that plane. Reactions of 2-aryl-1-benzoyl-1-nitroethenes with pyrrole and N-methylpyrrole gave the corresponding alkylation products at the C2 atom in the heteroring.

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Authors and Affiliations

  1. Hertzen Russian State Pedagogical University, nab. r. Moiki 48, St. Petersburg, 191186, Russia

    V. M. Berestovitskaya, R. I. Baichurin, N. I. Aboskalova, G. A. Berkova & A. V. Fel’gendler

  2. Nesmeyanov Institute of Organometallic Compounds, Russian Academy of Sciences, ul. Vavilova 28, Moscow, 119991, Russia

    K. A. Lysenko

Authors
  1. V. M. Berestovitskaya
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  2. R. I. Baichurin
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  3. N. I. Aboskalova
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  4. K. A. Lysenko
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  5. G. A. Berkova
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  6. A. V. Fel’gendler
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Corresponding author

Correspondence to V. M. Berestovitskaya.

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Original Russian Text © V.M. Berestovitskaya, R.I. Baichurin, N.I. Aboskalova, K.A. Lysenko, G.A. Berkova, A.V. Fel’gendler, 2009, published in Zhurnal Obshchei Khimii, 2009, Vol. 79, No. 10, pp. 1697–1702.

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Berestovitskaya, V.M., Baichurin, R.I., Aboskalova, N.I. et al. α-Nitro chalcones: Structure and reaction with pyrrole. Russ J Gen Chem 79, 2191–2196 (2009). https://doi.org/10.1134/S1070363209100181

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  • DOI: https://doi.org/10.1134/S1070363209100181

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