Skip to main content
SpringerLink
Log in

Imidophosphinate complexes of lanthanides. Investigation of thermochemical properties

  • Published:
Russian Journal of General Chemistry Aims and scope Submit manuscript

Abstract

New imidodiphosphinate complexes of neodymium and holmium of the general formula Ln[Ph2P(O)NP(O)Ph2]3 were synthesized. Results of investigation of their properties by means of differential scanning calorimetry, mass spectrometry, and the effusive Knudsen method are presented. Thermodynamic parameters of melting and sublimation are calculated.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Kido, J. and Okamoto, Y., Chem. Rev., 2002, vol. 102, p. 2357.

    Article  CAS  Google Scholar 

  2. Stathatos, E., Lianos, P., Evgeniou, E., and Keramidis, A.D., Synth. Met., 2003, vol. 13, p. 433.

    Article  Google Scholar 

  3. Katkova, M.A., Vikhtunovskii, A.G., and Bochkarev, M.N., Usp. Khim., 2005, vol. 74, no. 12, p. 1193.

    Google Scholar 

  4. Lin, Q., Liang, H.J., Zheng, Y.X., Wang, Q.G., and Cou, L.Ch., Thin Solid Films, 2001, vol. 396, p. 191.

    Article  CAS  Google Scholar 

  5. Christou, V., Salata, O.V., Ly, T.Q., Capecchi, S., Bailey, N.J., Cowley, A., and Chippindale, A.M., Synth. Met., 2000, vol. 7, p. 111.

    Google Scholar 

  6. Hohne, G.W.H., Hemminger, W.F., and Flammersheim, H.F., Differential Scanning Calorimetry, Springer-Verlag, Berlin, Heidelberg, 2003, p. 299.

    Google Scholar 

  7. Semyannikov, P.P., Igumenov, I.K., Trubin, S.V., Chusova, T.P., and Semenova, Z.I., Thermochim. Acta, 2005, vol. 432, p. 91.

    Article  CAS  Google Scholar 

  8. Wang, F.T., Naidzionek, J., Lenekev, K.L., Wasserman, H., and Braitsch, D.M., Synthesis and Reactivity in Inorganic and Metallorganic Chemistry, 1978, vol. 8, no. 2, p. 119.

    Article  CAS  Google Scholar 

  9. Bradley, D.C., Chotra, J.S., and Hart, F.A., J. Chem. Soc., Dalton Trans., 1973, no. 10, p. 1021.

Download references

Author information

Authors and Affiliations

  1. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, ul. Tropinina 49, Nizhnii Novgorod, 603950, Russia

    Yu. A. Efimova, B. I. Petrov, G. A. Abakumov, A. A. Logunov, M. E. Burin & M. A. Katkova

  2. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    P. P. Semyannikov

Authors
  1. Yu. A. Efimova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. B. I. Petrov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. G. A. Abakumov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. A. Logunov
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. M. E. Burin
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. M. A. Katkova
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. P. P. Semyannikov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to B. I. Petrov.

Additional information

Original Russian Text © Yu.A. Efimova, B.I. Petrov, G.A. Abakumov, A.A. Logunov, M.E. Burin, M.A. Katkova, P.P. Semyannikov, 2009, published in Zhurnal Obshchei Khimii, 2009, Vol. 79, No. 8, pp. 1283–1286.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Efimova, Y.A., Petrov, B.I., Abakumov, G.A. et al. Imidophosphinate complexes of lanthanides. Investigation of thermochemical properties. Russ J Gen Chem 79, 1641–1644 (2009). https://doi.org/10.1134/S107036320908009X

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S107036320908009X

Keywords

Search

Navigation