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Structures of two complexes of neodymium(III) and holmium(III) with dipivaloylmethane

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Abstract

The structure of two lanthanide (Ln = Nd, Ho) complexes with dipivaloylmethane (Hdpm) is studied at 150(2) K by single crystal X-ray diffraction. The crystallographic data are as follows for [Nd(dpm)3]2: space group P21/n, a = 12.3281(3) Å, b = 27.8118(6) Å, с = 21.9035(5) Å, β = 105.241(1)°, V = 7245.8(3) Å3, Z = 4, R = 0.0333; for [Ho(dpm)3]2: space group P21/n, a = 12.2067(6) Å, b = 27.5626(13) Å, с = 21.8624(10) Å, β = 105.188(1)°, V = 7098.6(6) Å3, Z = 4, R = 0.0321. Both structures are molecular and consist of neutral [Ln(dpm)3]2 dimeric molecules. The thermogravimetric studies demonstrate that Ln(dpm)3 volatility increases in the series from [La(dpm)3]2 to Yb(dpm)3.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    P. A. Stabnikov, S. A. Mosyagina, K. V. Zherikova, I. V. Korol′kov, N. V. Pervukhina & N. B. Morozova

  2. Novosibirsk National Research State University, Novosibirsk, Russia

    S. A. Mosyagina, I. V. Korol′kov & N. V. Pervukhina

Authors
  1. P. A. Stabnikov
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  2. S. A. Mosyagina
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  3. K. V. Zherikova
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  4. I. V. Korol′kov
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  5. N. V. Pervukhina
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  6. N. B. Morozova
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Correspondence to P. A. Stabnikov.

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Original Russian Text © 2017 P. A. Stabnikov, S. A. Mosyagina, K. V. Zherikova, I. V. Korol′kov, N. V. Pervukhina, N. B. Morozova.

Translated from Zhurnal Strukturnoi Khimii, Vol. 58, No. 8, pp. 1743-1746, November-December, 2017.

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Stabnikov, P.A., Mosyagina, S.A., Zherikova, K.V. et al. Structures of two complexes of neodymium(III) and holmium(III) with dipivaloylmethane. J Struct Chem 58, 1693–1696 (2017). https://doi.org/10.1134/S0022476617080327

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  • DOI: https://doi.org/10.1134/S0022476617080327

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