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New viologen analogs: 1,4-bis[2-(pyridin-4-yl)ethenyl]benzene quaternary salts

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Abstract

Alkylation of 1,4-bis[2-(pyridin-4-yl)ethenyl]benzene with alkyl p-toluenesulfonates and dimethyl sulfate gave new viologen analogs, 1-alkyl-4-(2-{4-[2-(1-alkylpyridinium-4-yl)ethenyl]phenyl}ethenyl)-pyridinium bis(p-toluenesulfonates) and sulfate. Their derivatives with tetrafluoroborate and tetraphenylborate ions were also obtained. Spectral properties of the synthesized compounds were examined, and their structure was determined by X-ray analysis.

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Authors and Affiliations

  1. Institute of Organic Chemistry, National Academy of Sciences of Ukraine, ul. Murmanskaya 5, Kiev, 02660, Ukraine

    A. V. Gutov, E. B. Rusanov, L. V. Chepeleva, A. B. Ryabitskii & A. N. Chernega

  2. Taras Shevchenko Kiev National University, Kiev, Ukraine

    S. G. Garasevich

Authors
  1. A. V. Gutov
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  2. E. B. Rusanov
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  3. L. V. Chepeleva
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  4. S. G. Garasevich
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  5. A. B. Ryabitskii
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  6. A. N. Chernega
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Corresponding author

Correspondence to A. V. Gutov.

Additional information

Original Russian Text © A.V. Gutov, E.B. Rusanov, L.V. Chepeleva, S.G. Garasevich, A.B. Ryabitskii, A.N. Chernega, 2009, published in Zhurnal Obshchei Khimii, 2009, Vol. 79, No. 7, pp. 1156–1161.

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Gutov, A.V., Rusanov, E.B., Chepeleva, L.V. et al. New viologen analogs: 1,4-bis[2-(pyridin-4-yl)ethenyl]benzene quaternary salts. Russ J Gen Chem 79, 1513–1518 (2009). https://doi.org/10.1134/S1070363209070196

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  • DOI: https://doi.org/10.1134/S1070363209070196

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