Abstract
Superoxide ions were generated by the action of γ-radiation on water-alcohol solutions saturated with oxygen. The reaction of superoxide ions with sodium 2,4-dichlorophenoxyacetate and pentachlorophenol was studied. The reaction of O2 −• with chloroaromatic compounds results in elimination of chloride ions and formation of phenyl radicals active in elimination of hydrogen atoms. The rate constant of the reaction between O2 −• and 2,4-dichlorophenoxyacetate was calculated using the method of mathematical simulation.
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Original Russian Text © V.S. Kosobutskii, 2009, published in Zhurnal Obshchei Khimii, 2009, Vol. 79, No. 3, pp. 419–424.
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Kosobutskii, V.S. On the reaction of superoxide ion with organochloric compounds. Russ J Gen Chem 79, 408–413 (2009). https://doi.org/10.1134/S107036320903013X
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DOI: https://doi.org/10.1134/S107036320903013X